# Journal of Materials Science

## List of Papers (Total 382)

#### Conditions for the occurrence of acicular ferrite transformation in HSLA steels

For the class of steels collectively known as high strength low alloy (HSLA), an acicular ferrite (AF) microstructure produces an excellent combination of strength and toughness. The conditions for the occurrence of the AF transformation are, however, still unclear, especially the effects of austenite deformation and continuous cooling. In this research, a commercial HSLA steel was ...

#### Kinetics of vacancy annealing upon time-linear heating applied to dilatometry

A kinetic model for the diffusion-controlled annealing of excess vacancies under the experimentally relevant, non-isothermal condition of time-linear heating is presented and applied to dilatometry. The evolution of the vacancy concentration with time is quantitatively analyzed, considering as ideal sinks either dislocations or grain boundaries of spherical- or cylindrical-shaped ...

#### New composite gyrotropic double-negative metamaterial

This work is the continuation of our study started in Tralle et al. (J Appl Phys 115:233509, 2014). In it, we examined the possibility of fabricating the metamaterial in a relatively simple way. Our idea was to use the three-component mixture of ingredients, where one of them is responsible for the negative permeability $\mu (\omega )$ of hypothetical metamaterial, while the ...

#### Bi3TeBO9: electronic structure, optical properties and photoinduced phenomena

Improvement of the nonlinear optical properties, mainly photoinduced enhancement of effective second harmonic generation was observed in Bi3TeBO9 (BTBO) crystals under irradiation of two external UV laser beams. The effect is caused by an interaction of two coherent photoinducing beams of nitrogen laser with wavelength 371 nm near the Bi3TeBO9 fundamental edge, resulting in ...

#### Factors affecting the hygroexpansion of paper

Paper is a widely used packaging material and is nowadays regaining importance, e.g., as bio-based and biodegradable material. Moreover, new technologies such as polymer–fiber composites, printed electronics and the deep drawing of paper are developing. The process stability and also the resulting quality of paper converting processes such as coating, metallization, printing, and ...

#### Poly(ε-caprolactone)-based membranes with tunable physicochemical, bioactive and osteoinductive properties

In contrast to currently used materials, membranes for the treatment of bone defects should actively promote regeneration of bone tissue beyond their physical barrier function. What is more, both material properties and biological features of membranes should be easily adaptable to meet the needs of particular therapeutic applications. Therefore, the role of preparation methods ...

#### A self-organising biomimetic collagen/nano-hydroxyapatite-glycosaminoglycan scaffold for spinal fusion

The use of spinal fusion surgery as a treatment for degenerative spinal conditions and chronic back pain is increasing. However, this technique requires use of a bone grafting material to fuse the vertebrae, traditionally autologous bone, which consists of an optimal combination of osteogenic cell precursors, extracellular matrix proteins and mineral components. To date, this ...

#### Modelling of microstructural evolution in multi-layered overlay coatings

Functionally graded, multi-layered coatings are designed to provide corrosion protection over a range of operating conditions typically found in industrial gas turbines. A model incorporating diffusion, equilibrium thermodynamics and oxidation has been developed to simulate the microstructural evolution within a multi-layered coating system. The phase and concentration profiles ...

#### The synthesis and characterization of Cu2ZnSnS4 thin films from melt reactions using xanthate precursors

Kesterite, Cu2ZnSnS4 (CZTS), is a promising absorber layer for use in photovoltaic cells. We report the use of copper, zinc and tin xanthates in melt reactions to produce Cu2ZnSnS4 (CZTS) thin films. The phase of the as-produced CZTS is dependent on decomposition temperature. X-ray diffraction patterns and Raman spectra show that films annealed between 375 and 475 °C are ...

#### Understanding heterogeneity in Genesis diamond-like carbon film using SIMS analysis of implants

An amorphous diamond-like carbon film deposited on silicon made at Sandia National Laboratory by pulsed laser deposition was one of several solar wind (SW) collectors used by the Genesis Mission (NASA Discovery Class Mission #5). The film was ~1 μm thick, amorphous, anhydrous, and had a high ratio of sp 3–sp 2 bonds (>50%). For 27 months of exposure to space at the first Lagrange ...

#### Nickel sulfide thin films and nanocrystals synthesized from nickel xanthate precursors

Nickel sulfide thin films and nanocrystals stabilized with oleylamine ligands are prepared from two different nickel xanthates as single-source precursors, which decompose at approx. 180 °C, and are thereby converted into nickel sulfide. These nickel xanthates comprise branched alkyl moieties allowing the choice of a wide range of nonpolar organic solvents for the processing to ...

#### Effect of Cr addition on γ–γ′ cobalt-based Co–Mo–Al–Ta class of superalloys: a combined experimental and computational study

The present article deals with effect of Cr addition (10 at.%) on the partitioning behavior and the consequent effect on mechanical properties for tungsten-free γ–γ′ cobalt-based superalloys with base alloy compositions of Co–30Ni–10Al–5Mo–2Ta (2Ta) and Co–30Ni–10Al–5Mo–2Ta–2Ti (2Ta2Ti). Cr addition leads to a change in the morphology of the strengthening cuboidal-shaped γ′ ...

#### The structural parameters of rigid matrix of saccharide-based gel described by short and long diffusion regime analysis

The tortuosity–porosity relation and internal structure diameters in a selected organogel are studied. The diffusion coefficient measured by pulsed field gradient NMR at short and long observation times can be used to estimate the tortuosity and the pore surface-to-volume (S/V pore) ratio of a porous material (Latour et al. in J Magn Res A 112:83–91, 1995; Mair et al. in Magn Res ...

#### Thermal expansion coefficients in Invar processed by selective laser melting

This work investigates whether the unique low thermal expansion property of Invar (64Fe–36Ni) is retained after processing using the additive manufacturing process selective laser melting (SLM). Using this process, near-full-density components (99.96%) were formed by melting thin (20 μm) layers of powdered Invar (15–45 μm particle size). The mechanical properties of SLM Invar were ...

#### Kinetics of intermetallic phase growth and determination of diffusion coefficients in solid–solid-state reaction between Cu and (Sn+1at.%Ni) pads

The influence of nickel addition to tin substrate on microstructure, kinetics parameters as well as diffusion coefficients was studied on Cu/Sn diffusion couples. The results revealed that the presence of nickel did not affect the growth of Cu3Sn phase in comparison with that of the binary Cu/Sn diffusion couple. However, it substantially influenced the morphology and chemical ...

#### Charge-based deep level transient spectroscopy of B-doped and undoped polycrystalline diamond films

The undoped and B-doped polycrystalline diamond thin film was synthesized by hot filament chemical vapor deposition and microwave plasma, respectively. The structural characterization was performed by scanning electron microscopy, X-ray diffraction and Raman spectroscopy. The electrical properties of synthesized diamond layer were characterized by dc-conductivity method and charge ...

#### Three-dimensional in situ observations of compressive damage mechanisms in syntactic foam using X-ray microcomputed tomography

Syntactic foams with hollow glass microspheres embedded in an epoxy matrix are used in marine, aerospace and ground transportation vehicle applications. This work presents an in situ experimental study of failure mechanisms in syntactic foam based on X-ray microcomputed tomography with uniaxial compression. Under different levels of compressive strain, the material was scanned ...

#### On nanostructured molybdenum–copper composites produced by high-pressure torsion

Nanostructured molybdenum–copper composites have been produced through severe plastic deformation of liquid-metal infiltrated Cu30Mo70 and Cu50Mo50 (wt%) starting materials. Processing was carried out using high-pressure torsion at room temperature with no subsequent sintering treatment, producing a porosity-free, ultrafine-grained composite. Extensive deformation of the Cu50Mo50 ...

#### Mechanically activated metathesis reaction in NaNH2–MgH2 powder mixtures

The present work addresses the kinetics of chemical transformations activated by the mechanical processing of powder by ball milling. In particular, attention focuses on the reaction between NaNH2 and MgH2, specific case studies suitably chosen to throw light on the kinetic features emerging in connection with the exchange of anionic ligands induced by mechanical activation. ...