Groundwater flow dynamics in the complex aquifer system of Gidabo River Basin (Ethiopian Rift): a multi-proxy approach

Hydrogeology Journal, Nov 2016

Hydrochemical and isotope data in conjunction with hydraulic head and spring discharge observations were used to characterize the regional groundwater flow dynamics and the role of the tectonic setting in the Gidabo River Basin, Ethiopian Rift. Both groundwater levels and hydrochemical and isotopic data indicate groundwater flow from the major recharge area in the highland and escarpment into deep rift floor aquifers, suggesting a deep regional flow system can be distinguished from the shallow local aquifers. The δ18O and δ2H values of deep thermal (≥30 °C) groundwater are depleted relative to the shallow (<60 m below ground level) groundwater in the rift floor. Based on the δ18O values, the thermal groundwater is found to be recharged in the highland around 2,600 m a.s.l. and on average mixed with a proportion of 30 % shallow groundwater. While most groundwater samples display diluted solutions, δ13C data of dissolved inorganic carbon reveal that locally the thermal groundwater near fault zones is loaded with mantle CO2, which enhances silicate weathering and leads to anomalously high total dissolved solids (2,000–2,320 mg/l) and fluoride concentrations (6–15 mg/l) exceeding the recommended guideline value. The faults are generally found to act as complex conduit leaky barrier systems favoring vertical mixing processes. Normal faults dipping to the west appear to facilitate movement of groundwater into deeper aquifers and towards the rift floor, whereas those dipping to the east tend to act as leaky barriers perpendicular to the fault but enable preferential flow parallel to the fault plane.

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Groundwater flow dynamics in the complex aquifer system of Gidabo River Basin (Ethiopian Rift): a multi-proxy approach

C Groundwater flow dynamics in the complex aquifer system of Gidabo River Basin (Ethiopian Rift): a multi-proxy approach Abraham Mechal 0 1 2 4 Steffen Birk 0 1 2 4 Martin Dietzel 0 1 2 4 Albrecht Leis 0 1 2 4 Gerfried Winkler 0 1 2 4 Aberra Mogessie 0 1 2 4 Seifu Kebede 0 1 2 4 0 JR-AquaConSol GmbH, Elisabethstrasse 18/II , A-8010 Graz , Austria 1 Institute of Applied Geosciences, NAWI Graz Geocenter, Graz University of Technology , Rechbauerstrasse 12, A-8010 Graz , Austria 2 Institute of Earth Sciences, NAWI Graz Geocenter, University of Graz , Heinrichstraße 26, A-8010 Graz , Austria 3 Steffen Birk 4 School of Earth Sciences, Addis Ababa University , P.O. BOX 1176, Addis Ababa , Ethiopia Hydrochemical and isotope data in conjunction with hydraulic head and spring discharge observations were used to characterize the regional groundwater flow dynamics and the role of the tectonic setting in the Gidabo River Basin, Ethiopian Rift. Both groundwater levels and hydrochemical and isotopic data indicate groundwater flow from the major recharge area in the highland and escarpment into deep rift floor aquifers, suggesting a deep regional flow system can be distinguished from the shallow local aquifers. The δ18O and δ2H values of deep thermal (≥30 °C) groundwater are depleted relative to the shallow (<60 m below ground level) groundwater in the rift floor. Based on the δ18O values, the thermal groundwater is found to be recharged in the highland around 2,600 m a.s.l. and on average mixed with a proportion of 30 % shallow groundwater. While most groundwater samples display diluted solutions, δ13C data of dissolved inorganic carbon reveal that locally the thermal groundwater near fault zones is loaded with mantle CO2, which enhances silicate weathering and leads to anomalously high total dissolved solids (2,0002,320 mg/l) and fluoride concentrations (6-15 mg/l) exceeding the recommended guideline value. The faults are generally found to act as complex conduit leaky barrier systems favoring vertical mixing processes. Normal faults dipping to the west appear to facilitate movement of groundwater into deeper aquifers and towards the rift floor, whereas those dipping to the east tend to act as leaky barriers perpendicular to the fault but enable preferential flow parallel to the fault plane. Hydrochemistry; Stable isotopes; Groundwater flow; Ethiopia Introduction Groundwater is considered as a valuable freshwater resource that can be developed at relatively low cost and provides a buffer in times of drought (Masiyandima and Giordano 2007; Kebede 2013) . In the Ethiopian Rift, the development of groundwater resources still appears to be focused on shallow hand dug wells and unprotected springs used for community water supply. Except for in the Kobo and Raya valleys, where the comparative advantages of groundwater irrigation over rain-fed agriculture and surface water irrigation have been demonstrated, the use of groundwater from boreholes for irrigation has been almost non-existent until recently. Nevertheless, recently the use of shallow groundwater for commercial irrigation, as well as industrial use, has increased. The promise around accelerated use of groundwater for consumptive as well as productive use is hampered by lack of clear knowledge about the groundwater system. The reason for such poor knowledge in the Ethiopian Rift is partly related to the complex hydrogeological setting caused by the strong climate and physiographic difference, variability and lateral discontinuity of volcanic rocks, and the disruption of lithologies by faults. The Ethiopian Rift is part of the East Africa Rift System (EARS), the classic example of a continental rift where the Earth’s tectonic forces are currently trying to create new plates (Nubian and Somalian plates). As a consequence of the tectonic activity, typical rift morphology (uplifted highlands and downthrown flat plain rift floor) is well developed causing strong contrast in topography and climate within short distances. Likewise, during the development of the rift, widespread basaltic and rhyolitic volcanic activity has occurred since the Miocene (WoldeGabriel 1990; Chernet et al. 1998) . As a result of a series of volcanic activities at different places and times, the stratigraphic sequences are vertically and laterally highly variable. In addition, the volcanic rocks are highly dissected by faults. Two normal fault systems can be distinguished: the roughly NE–SW trending rift boundary faults and a NNE–SSW oriented set of faults affecting the rift floor usually referred to as the Wonji Fault Belt (WFB; e.g. Boccaletti et al. 1998; Mohr 1962) . The level of complexity of the hydrogeological setting is highly variable from region to region in the Ethiopian Rift. Some studies (Ayenew 1998; Ayenew et al. 2009; Kebede et al. 2008, 2010; Bretzler et al. 2011) in different sectors of the Ethiopian Rift showed that they share common characteristics in regard to recharge pattern, groundwater flow direction, hydrochemical evolution and isotopic trends from the highland towards the rift floor. However, the rate of recharge, flow and mineralization, depth of circulation, spatial heterogeneity and interconnectivity of aquifers are different in the distinct sectors of the Ethiopian Rift and show their own peculiar characteristics. For instance, one of the serious problems related to groundwater use in the Ethiopian Rift is poor water quality associated with high salinity and fluoride level (Chernet 1982; Darling 1996; Gizaw 1996; Chernet et al. 2001; Reimann et al. 2003; Tekle-Haimanot et al. 2006) . The salinity and fluoride levels of the groundwater vary significantly from place to place, ranging from fluoride-free freshwaters to more saline fluoride-rich waters. Likewise, aquifer productivity and water-table depth vary significantly over short distances (Chernet 1982; Ayenew et al. 2008; Furi et al. 2011) . A sound understanding of the regional and local hydrogeological setting is therefore required for an adequate development of groundwater resources in the Ethiopian Rift. To improve the knowledge about the hydrogeological setting and groundwater flow in the southern Main Ethiopian Rift (MER) Gidabo River Basin was selected as a study area representing the south eastern flank of the MER. This area is characterized by wide topography and climate variation ranging from humid in the highland to semi-arid in the rift floor (Mechal et al. 2015) , very complex lithological units (laterally discontinuous and intermixed) and intense faulting. As a result, the hydrodynamics is likely controlled by the heterogeneity of the aquifers and geological structures, which complicates the development and effective use of the groundwater resources. Hydrogeological investigations have been focused mainly on the central MER. In contrast, the existing hydrogeological studies in the Gidabo River Basin, have been reconnaissance surveys and limited to groundwater resource assessment (Raunet 1977; Negussei 1990; Yasin 2002; AG consult 2004; Mechal 2007; Mussie 2007; Debisso 2009) . Only recently, Mechal et al. (2015) employed a hydrological model to assess the spatial and temporal recharge distribution within Gidabo River Basin. Using a highly simplifying twodimensional (2D) groundwater flow model, Mechal et al. (2016) showed that measured groundwater levels and the knowledge about the general trends of the hydraulic properties within the basin are consistent with the spatial recharge distribution from the hydrological model; yet, very little is known about the detailed hydrogeology of the area. The primary objective of this research therefore is to understand the groundwater flow dynamics and the functioning of faults in the Gidabo River Basin, including (1) the hydrochemical evolution, (2) the impacts of tectonic setting of the rift, and (3) finally a conceptual hydrogeological model of the functioning of the Gidabo River Basin. For this purpose, a multi proxy approach using hydrochemical and isotopic tracers in conjunction with hydraulic head and spring discharge observations is applied. This includes the interpretation of hydrochemical and isotope data (δ2H, δ18O, and δ13C) to characterize the chemical evolution of groundwater and the mixing of different flow components (e.g. Clark and Fritz 1997; Herczeg et al. 2001) . These techniques were previously employed for investigations of the hydrogeology of active rift systems such as the East African Rift, Dead Sea Rift and Rio Grande Rift (Salameh and Rimawi 1984; Kebede et al. 2008; Chowdhury et al. 2008; Bretzler et al. 2011) . In such tectonic settings, variable lithology due to different episodes of volcanic eruptions, high geothermal gradients and emergence in the rift of mantle gases (e.g. CO2) escaping through fault zones are very common and may result in a wide range of groundwater compositions. On one hand, major ion chemistry can be used to decipher the major processes controlling the groundwater composition (Darling 1996; Gizaw 1996; Rango et al. 2009) ; however, on the other hand, stable isotopes (δ2H, δ18O) have mostly conservative properties and depend strongly on atmospheric conditions during recharge (Gat 1971). Consequently, they provide information about the recharge processes, groundwater flow paths and mixing processes (Fontes 1980; Rose et al. 1996; Mazor 2004) . The combined interpretation of groundwater chemistry and environmental isotopes (e.g. Bethke and Johnson 2008; Leray et al. 2012) thus helps to constrain groundwater flow paths across fault zones and is also helpful to identify different groundwater flow systems. Yet particularly in complex hydrogeological settings where groundwater flow is largely controlled by geological structures, the results from hydrogeochemical and isotopic approaches might be ambiguous; therefore, it is desirable to combine hydraulic head observations with environmental tracers (Bense et al. 2013) . The hydraulic head distribution can be used to understand the directions of groundwater flow at the fault zone (e.g. Haneberg 1995; Bense et al. 2003, 2008; Bense and Person 2006; Anderson and Bakker 2008) and thus provides an indication of the hydrogeological behavior of the fault zones. In this report, therefore, a combined multi-tracer and hydraulic approach is provided for the hydrogeological characterization of a complex rift aquifer system. Descriptions of the study area Location, physiography and climate The study area, Gidabo River Basin, is located in southern Ethiopia in the eastern margin of the MER (Fig. 1). The River Gidabo is the second largest river flowing to Lake Abaya, the largest lake in the Ethiopian Rift, with a 3,302 km2 drainage area, which extends from the center of the rift floor to the mountains of the rift boundary. The physiographic features of the MER are mainly the results of faulting and volcanism associated with rifting processes. In the southern sector of the MER, where the Gidabo River Basin is located, the collapse of the rift took place fairly regular in a single block. As a result, the typical rift morphology is well developed and the three major physiographic regions, rift floor, escarpment and highland, are clearly visible. The major tectonic scarp connects the rift floor with the uplifted plateau; the plateau rises to elevations of 3,200 m a.s.l. (Gelala Mountain), whereas the rift floor descends regularly into the Lake Abaya, where it lies at 1,175 m a.s.l. Local increases in the elevation of the rift floor are generally due to volcanic edifices and step faulting. The drainage system of the basin is strongly influenced by the morphology, which in turn is dependent on the geological phenomena. The stream networks commonly show a dendritic drainage pattern and the flow is east–west almost perpendicular to the strike of the escarpment in the upstream; however, in the rift floor the flow deflects to the southwest–northeast direction and displays a sub parallel pattern in the down course sections. There seems to be a strong relationship between the main stream course and geologic structures in the area, especially in the rift floor (Fig. 1). The climate is highly variable in the Gidabo River Basin and gradually changes from semi-arid in the rift floor to humid in the mountains. In the highlands and escarpment bounding the rift floor, rainfall exceeds 1,600 mm/year, whilst the lowest elevation of the rift floor receives much less rainfall, often below 800 mm/year. Precipitation is characterized by a bimodal pattern with a maximum during April and May (small rain season) and a subordinate peak in September and October (heavy rain season). The diurnal variation of temperature in the basin is more visible than its seasonal variation. The average monthly temperature varies from 21 to 25 °C in the lowlands to less than 11.5–13.5 °C in the high elevation plateau. Geological setting Being situated in the Ethiopian Rift, the geological cover of the study area (Fig. 1) is the product of a series of volcanic eruptions since the Miocene (WoldeGabriel et al. 1990) . In general, the rocks covering the area fall into three major groups: pre-rift volcanic rocks, rift volcanic rocks and post rift sediments. The most important features of these rocks together with the geological structure are compiled from current and previous studies (Mohr 1962; Raunet 1977; WoldeGabriel et al. 1990; Boccaletti et al. 1998; Acocella et al. 2003; AG consult 2004; Korme et al. 2004; Kurz et al. 2007; Mechal 2007; Halcrow 2008; GSE 2012) and summarized, as follows, from the oldest to the youngest. The pre-rift rocks (Oligocene–middle Miocene) occur mainly in the escarpment and highland and to a lesser extent in the rift floor. This group mainly comprises basalt (PV) and ignimbrite (PNV) and represents the oldest rocks in the area, likely separated from the underlying basement by the residual sandstone to the south of the catchment. Rift volcanic rocks (upper Miocene–Pleistocene) are mainly exposed in the rift floor and dominated by silicic volcanic rocks. A thick succession of stratoid silicics comprising predominantly ignimbrites with subordinate unwelded tuffs, ash flows, rhyolites and trachytes, which is commonly known as the Nazret group (N12n), form parts of the rift floor and also outcrops in the escarpment and highland. In the rift floor, the Nazret group is unconformably overlain by younger volcanic rocks called the Dino formation which comprises coarse unwelded pumiceous pyroclastics (Qdp) and a complex mixture of different pyroclastic materials such as ash, tuff and ignimbrite (Qdi). Rhyolitic lava flows, composed of stratified ash, pumice and rhyolite flows (Qwa) mainly occur to the north of Lake Abaya along the axial zone of the rift but similar prominent volcanoes also have erupted pumice and unwelded tuffs forming volcanic mountains in the highland (Qws). Post-rift sediments (Holocene) such as alluvial (Qa) and lacustrine sediments (Qvs) mainly occur along the lower reaches of the Gidabo River and as patchy deposit along the axial zone of the rift, respectively. The volcanic sequences and sediments in the area are densely dissected by extensional fault systems resulting from the rifting process (Fig. 1). The major fault types are normal faults having generally similar strike but some dip to the east and others to the west. Chronologically they can be grouped into two distinct fault systems: the older Oligocene–Miocene NE–SW trending fault system which characterizes mainly the rift margin, and the younger Quaternary-present NNE–SSW trending set of faults affecting the rift floor, usually referred to as the Wonji Fault Belt (WFB; e.g. Boccaletti et al. 1998; Mohr 1962) . The rift margin is well developed and it is defined by a more or less continuous system of boundary faults with a single vertical displacement (>1,000 m) to the rift floor, whereas the rift floor faults are characterized by short, closely spaced, active faults that exhibit minor vertical throw (5–100 m; e.g. Boccaletti et al. 1998). WFB structures are well developed in the northwestern part of the catchment where right-stepping faults and horst-graben structures are very common (Fig. 1). At places, open fissures with or without vertical displacement are also very common in association with the faults. Main geological units and major stratigraphic sequences with associated fault systems are shown in Fig. 1. Hydrogeologic setting The hydrogeology of the Gidabo River Basin is complex due to the geometry of the rift, the variability and lateral discontinuity of the volcanic rocks, and the disruption of lithologies by faults. The large topographic differences in the area result in a highly heterogeneous distribution of rainfall and great differences in air temperature causing a highly heterogeneous spatial distribution of groundwater recharge within the catchment. The long-term annual average recharge is estimated to be approximately 236 mm/year but reveals a remarkable decrease from the highland (410 mm/year) towards the rift floor (25 mm/year) reflecting mainly the great differences in climatic conditions (Mechal et al. 2015) . Likewise, the aquifers of the area show vertical as well as lateral heterogeneity. The aquifers are largely the product of volcanic eruptions which occurred in the area at different times and different locations (WoldeGabriel et al. 1990, 2000) ; and as a result, the rocks have been subjected to different degrees of weathering and fracturing. Between the different eruption time periods, the rocks have been weathered and eroded with subsequent deposition of alluvial materials resulting in multi-layer aquifers with a range of unconfined to semi-confined layers. The interpretation of pumping tests and well lithologic data (e.g. SWWCE, Awasa, Ethiopia, unpublished report, 2012) obtained from Sidama, Gedeo and Borena Zone Water Resource Development Offices show that interlayered weathered and fractured basalts and ignimbrites are the major aquifers in the highland and escarpment, whereas a mixture of pyroclastic flows (ignimbrite, pumice, tuff and ash) as well as alluvial and lacustrine deposits are the dominant aquifers in the rift floor. Lithologic logs of some selected boreholes in the highland, escarpment and rift floor are presented in Fig. 2. The thickness of the laterally discontinued multi-layer aquifers varies between a few meters to 30 m. In general, unconfined aquifers overlay multiple semi-confined aquifers, and locally in the rift floor artesian aquifers give rise to flowing wells. The transmissivity of the aquifers ranges from 50 to 1,100 m2/day and generally increases from the highland towards the rift floor. This can be attributed to the increase in the intensity of the fracturing due to tectonic movement towards the rift floor and the occurrence of highly permeable rocks such as pumice and aluvio-lacustrine sediments in the rift floor (Fig. 1). In general, the lithological variations coupled with varied degrees of weathering and fracturing create a high degree of heterogeneity. Methods and materials In two field campaigns (winter 2012 and 2013) , structural mapping, water level and spring discharge measurements and water sampling were carried out. Prior to the field investigation, geological structures (lineaments) were delineated by superimposing shaded relief images created from digital elevation models (DEMs) and existing structural maps. The interpretations made were transferred to topographic maps of the same scale later to be checked in the field. Spring discharge and water level measurements were made in a well-distributed manner in the catchment. Spring discharge measurements were conducted on the developed springs for drinking and domestic water uses. The discharge (l/s) was estimated using a bucket and a stopwatch (volume of the bucket/time to fill the container). Similarly, the groundwater level data were obtained from existing pumping wells for local water supply. When visiting the wells, the location and the elevation were determined using the global positioning system (GPS); the accuracy of which was on the order of 3–5 m. The water level in the well was measured using a dipmeter (Brassington 2007) . Before measuring the water level, pumping wells were stopped to allow recovery. An effort was made to search for wells in fault zones and special attention was given during water level measurement for wells placed in the up and down thrown blocks of the faults. Water samples were taken approximately along NE–SW and E–W transects for both isotope and hydrochemical analyses, yielding a total of 57 water samples for the Gidabo River Basin. The samples were collected from rivers (3), springs (14), and wells (40). Prior to sample collection, inactive wells had been pumped for 15 min to remove the water stored in the well and ensure sampling of primary groundwater; the samples were collected while the pump was running. At springs the water was sampled using a plastic syringe. Separate samples were taken for the analysis of major ions and isotopes of water (δ2H and δ18O) and dissolved inorganic carbon (δ13CDIC). Immediately after sampling, the solutions were filtered through 0.45-μm membranes, subsequently stored in polyethylene (HDPE) bottles, and lastly sealed with double caps. Samples for cation analysis were preserved by adding ultra-pure 6N HNO3 to the water samples. For carbon isotope analyses (δ13C) of DIC, a 1-ml water sample was injected into a 10-ml gas-tight vial using a syringe and hollow needle. Prior to going into the field, the vials were preloaded with 0.1 ml of 100 % phosphoric acid, capped and the headspace flushed with He gas in the laboratory ( Spötl 2005 ). During sampling, field data such as pH, electrical conductivity (EC) and temperature, were recorded. Total alkalinity was measured in situ by titration with 0.1 N HCl using methyl orange as the indicator. Major ions samples were analyzed in the laboratory of the Graz University of Technology, Austria. Dissolved cations (Na, K, Mg and Ca) were analyzed using inductively coupled plasma optical emission spectrometry (ICP-OES; Perkin Elmer 4300). Anions (F, Cl, SO4 and NO3) were measured by ion chromatography (IC; Dionex 600). Isotopic composition of DIC was analyzed using a fully automated peripheral continuous-flow gas preparation device (Gasbench II), which was connected to a Finnigan DELTAplus XP mass spectrometer. The oxygen and hydrogen isotopic composition of the water samples were measured by a liquid-water isotope analyzer (LWIA) in the hydrogeological laboratory of the Addis Ababa University, Ethiopia. LWIA measurements are based on high-resolution laser absorption spectroscopy Boff-axis integrated cavity output spectroscopy^ (OA-ICOS). The sampling locations are shown in Fig. 3. The study area is subdivided into three physiographic regions—the highland, escarpment and rift floor—based on the DEM and the geomorphology of the study area. Samples in each physiographic region are grouped into three categories depending on the depth and temperature of groundwater: shallow, deep and thermal groundwater. Samples from springs (cold), rivers, and wells with depth ≤60 m below the ground level (b.g.l.) are classified as shallow circulating groundwater, while wells with depth ≥60 m b.g.l are considered as deep circulating groundwater. Groundwater ≥30 °C is considered thermal groundwater. Results and discussion Hydraulic data Spring discharge Gidabo River Basin is rich in springs both cold and thermal— Fig. 4 and Table S1 of the electronic supplementary material (ESM). The cold springs are very common along the escarpment and are either the result of short breaks in topography (depression springs) or of highly permeable weathered and fractured rocks overlying less permeable rocks (contact springs). Thermal springs are clustered in the rift floor. All thermal springs occur along the faults dipping eastward. In contrast, no groundwater discharge is observed along the westward dipping faults (Fig. 4). The thermal springs are the result of deep artesian aquifers intersected by NNE–SSW trending normal faults. The occurrence of thermal springs only on the eastward-dipping faults suggests that these type of faults not only act as a barrier for flow perpendicular to the fault, but also as a conduit parallel to the fault plane, which further suggests that the westward dipping faults facilitate the deep circulation of the groundwater in the general flow direction towards Lake Abaya. The field investigation conducted includes discharge measurements of some of the enhanced springs for drinking and domestic water uses (Fig. 4). Almost all springs discharge water throughout the entire year, even during dry seasons; however, their yield highly fluctuates with seasons. The high elevation (highland and escarpment) springs are numerous but have lower discharge (<0.5 l/s) than the low elevation (rift floor) springs with a maximum of 150 l/s. In the rift floor, in association with cold springs, thermal springs with a discharge between 6 and 15 l/s also exist. Although the high elevation springs are very abundant, their cumulative discharge is much less than that of the rift floor springs, which suggests that there are flow paths from the plateau and escarpment (where recharge is high) towards the rift floor (where recharge is low) that provide a large volume of water (mountain-block recharge). Fig. 3 Spatial distribution of sampling points in the Gidabo River Basin—the green irregular lines mark the physiographic regions: highland (2,400–3,207 m a.s.l.), escarpment (1,800– 2,400 m a.s.l.) and rift floor (1,170–1,800 m a.s.l.) Groundwater level Groundwater levels in the study area were found to be variable but the depth to groundwater generally shows an increasing trend from the highland towards the rift floor. The depth to static water level in the highland and escarpment ranges from just below the land surface to approximately 40 m b.g.l., while in the rift floor it varies from artesian conditions to 244 m b.g.l. The maximum water level depth was mapped in the northwestern sector of the rift floor. Figure 4 presents the resulting Gidabo River Basin watertable map. Where limited head observations are available, points of high-yield perennial spring emergence, which are believed to be connected to the static water level, have been used to represent the water level. The interpolated water level demonstrates that steep gradients occur in the escarpment and highland, while shallow gradients occur in the rift floor, which reflects the general topography of the catchment as well as the spatial heterogeneity of the volcanic rocks and spacing and distribution of fractures in the studied region. The steep hydraulic gradients are due to the steep slope and the presence of the relatively low-permeability volcanic rocks in the highland and escarpment, while the low gradients are associated with highly permeable fractured pyroclastic rocks in the flat plains of the rift floor. In general, the equipotential lines indicate the groundwater flows regionally from upland areas in the east towards Lake Abaya, which corresponds to the surfacewater flow direction; thus, the general groundwater flow direction is controlled by the topography. Close to Lake Abaya however, the equipotential lines appear to indicate groundwater flow toward an area south of where the river flows into the lake. Mechal et al. (2016) therefore assumed that the groundwater basin does not coincide with the surface-water divide in this area but extends further southward along the lake. Groundwater flow in this part of the catchment appears to be affected by the faults (see geological structures in Fig. 4). Yet, the low number of wells does not permit a more detailed investigation of the flow pattern in this area. Groundwater chemical composition The physico-chemical parameters of the analyzed groundwater samples from the Gidabo River Basin are given in Table 1. Groundwater temperature and the total dissolved solids (TDS) content show extreme variability; however, a clear pattern is observed from the highland towards the rift floor. In the catchment, the temperature of groundwater varies from 14 to 68 °C, while TDS varies from 30 to 2,320 mg/l. Both temperature and TDS show a gradual increase from the highland to the rift floor (Fig. 5a,b) with local anomalies related to thermal waters having high TDS (2,000–2,320 mg/l). The anomalous chemical composition of these involves high fluoride levels (6–15 mg/l) exceeding the guideline value of 1.5 mg/l recommended by WHO (2011) . Yet, the majority of groundwater in the Gidabo River Basin displays rather diluted solutions with TDS and fluoride concentrations below 375 and 1.5 mg/l, respectively. The increase in temperature from the highland towards the rift center is related to an increase in air temperature and geothermal gradient. Groundwater temperature in the deep rift floor aquifers is shifted by more than 10 °C from the local air temperature, suggesting the connection of these waters to the deep regional groundwater circulation (Fig. 5a). Water–rock interaction along the flow path from the highland towards the rift floor is a likely cause of the observed increase of TDS (Fig. 5b). Mixing with more saline water from deeper horizons or evaporation may also be potential explanations, which will be evaluated by the isotopic composition of the water itself below. Evaporation also results in increasing solute concentrations and can be assessed from chloride and sulfate concentrations. In the absence of chloride and sulfate minerals, these ion concentrations are governed by evaporation rather than by rock– water interaction (e.g. Dogramaci et al. 2015) . While chloride and sulfate concentrations are quite low in most waters, the elevated concentrations in the swampy area close n 2 tiisse 31CCO A A A A A .811 A .118 A .513 A A A A A A A .023 A .121 .625 A .029 A A A A A .316 A .135 A A .108 A δ N N N N N − N − N − N N N N N N N − N − − N − N N N N N − N − N N − N g n il IC p D n i trea −O3 .3 .62 .3 .7 .6 LD LD LD LD .5 .6 LD .00 LD LD .1 .13 .9 LD LD .3 .7 .00 .2 .4 .7 LD .0 LD LD .1 .2 .48 .2 .6 w N 0 1 2 2 0 B B B B 6 0 B 5 B B 0 1 1 B B 0 8 1 0 4 1 B 3 B B 0 0 3 0 5 e e s ( il(ececahhTmm litcaoyL ()anogoEW tr()eaboEG r()eaebkdoHA ilrf()eeeakET f()aaSFR ijir()eeakFTRm ii()cabhFRD i()eodkSTOm lreeaeaogbSmm lil()caoohFRG lil()caoohSTG ii()cabhFRD ()egoFFR rracngooooDm ir()ecadhSTM fcacounhhoR )(eboED lr)seaeeagHm tleanoodwA r()saauBH ti()eknuEH j()aaoEGm lir()aegEYm i()ayodEG r()aaFRW - ()ehuFRCm t()eeaannFRW tt()eenSTA ilr()aaeFSSR l()seaehbSTC ()sseeSTD ()-FR lr()aaeokFRwA ()obuFRY 2 O 31CC A .416 A .714 .516 .029 .024 .128 .918 A .123 .619 .912 .024 .222 A .74 .48 .166 A A A δ N − N − − − − − − N − − − − − N − − − N N N C I D r e v 8O .4 .7 .1 .4 .5 .4 .4 .1 .6 .7 .4 .7 .4 .5 .3 .9 .2 .5 .0 .4 ir 1 1 2 2 1 1 1 1 1 1 A 1 2 1 2 1 A 3 1 2 1 1 1 δ − − − − − − − − − N − − − − − N − − − − − − R , g L L L in −F .40 .70 .21 .20 .52 .10 .10 .20 BD .10 .30 .31 .10 .10 BD .10 .511 .491 .62 BD .10 .10 sp r t o h − 3 ) T(°C .652 .222 .682 .042 .532 .901 .801 .382 .801 .981 .552 .752 .901 .401 .032 .561 .066 .716 .534 .419 .020 .023 BD,re iachp u r ..l) tra iog s e s . p y a h em p (m 1 4 9 3 2 8 1 3 0 6 6 2 9 3 8 4 4 7 8 0 1 0 t e v 3 1 7 7 5 2 5 0 8 5 8 9 2 8 3 4 1 2 9 5 8 0 T th leE ,17 ,18 ,17 ,18 ,15 ,19 ,21 ,15 ,22 ,18 ,16 ,16 ,19 ,26 ,17 ,28 ,14 ,14 ,16 ,27 ,16 ,12 ,isd tea l c 407 913 069 838 583 530 006 597 462 352 397 134 119 612 062 176 357 492 659 998 598 461 sdo iind Y 557 067 077 857 907 996 617 307 637 137 347 277 857 557 507 317 117 607 647 157 647 017 levo tino s a 5 0 2 7 1 4 2 3 4 8 4 0 7 6 3 1 9 7 0 3 7 3 is c 87 48 69 66 64 53 72 52 12 76 18 99 72 87 30 34 65 00 37 60 07 66 ld lo 03 23 83 14 42 41 63 02 34 43 23 63 54 45 62 14 12 91 23 65 13 60 tao ign X 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 t l p S m ) D a ) F ) T s it)(cenduno tilacyoL ifrrr(aaeaanoFRDm l()aabonoFRA lr()eceahuduFRN l)(soobEO tlli()anoFRwD i()seaknoEM l()eaeedbhSE i(aaabugnudyRwG ()saaeknEH til()seeoEB (aacachdnhoFRwA i()caahnFFRw l()aaagbonoboEG ltr()aeeebbowHH ti)(saoSE r()eeakodbAH i(r)sseoSTB i()ekdoSTOm li(r)aegSTYm ifr()saaohHH t()soopFRA )(rreoFRA lveE,lti:tiseeanovon tiittrsssaeacedohhw 1 0 4 ia te 1 6 7 4 2 7 1 5 8 9 5 0 6 1 2 3 v t leab tiIeD -12H -12H -22H -32H -25H -7PS -2PS -2PS -3PS -4PS -8PS -9PS -9PS -1PS -1PS -1PS -1PS -4PS -5SP -1 -2 -3 rebb leeh T S B B B B B C C C C C C C C C C C H H H R R R A T Fig. 5 Spatial variation in groundwater a temperature and b TDS from the highland to the rift floor. The relationship of air temperature and elevation in the catchment is represented by: Air temp (°C) = −0.0053 Elev (m) + 28.05 to Lake Abaya indicate local effects of high evaporation (e.g. BH-51; see Fig. 3 and Table 1). Like temperature and TDS, pH shows a positive trend towards the rift, from acidic (pH 5.2) in the uplands to semi-alkaline (pH 8) in the deep rift floor groundwater. Similarly, the major dissolved ions show a wide variability across the watershed (Fig. 6). The variability in cation concentrations is more noticeable than that in the anion concentrations. Ca2+ is the dominant cation followed by Mg2+ in the highland aquifers but their relative contribution to the total solute content gradually decreases towards the rift floor (Fig. 7). In contrast, Na+ displays an increasing trend from the highland to the rift floor. The K+ concentration is normally low but shows a positive trend with groundwater temperature; K+ is the second dominant cation in the thermal groundwater system. As chloride and sulfate concentrations in the groundwater are mostly low, the dissolved anions are almost exclusively dominated by HCO3−. The measured HCO3− concentrations indicate an increasing trend from the highland towards the rift floor which corresponds to the increase in Na+ and K+ (Fig. 7). In general, the regional trends in TDS (Fig. 5b) and in the Piper diagram (Fig. 7) indicate a hydrochemical evolution from slightly mineralized Ca–Mg– Fig. 6 Variability of chemical composition of the groundwater (n = 57). Q1, Q2 and Q3 represents the first, the second and the third quartile, respectively HCO3 to moderately mineralized Ca/Na–HCO3 and finally to highly mineralized Na–HCO3 waters along the flow path from the highland to the rift floor. The major processes controlling the hydrochemical evolution of groundwater in Gidabo River Basin thus appear to be similar to those described elsewhere in the MER (UNDP 1973; Darling 1996; Gizaw 1996; Rango et al. 2009) . The dominant hydrochemical process is silicate hydrolysis, which leads to the release of cations like Ca2+, Mg2+, K+ and Na+ and the balancing bicarbonate ion into the groundwater. As the silicate hydrolysis in the study area is controlled by the uptake of gaseous CO2, the HCO3− content is related to concentrations of dissolved cations. This can easily be recognized by the strong correlation of cationic species [Na+ + K+ + Mg2+ + Ca2+] and [HCO3−], suggesting that the cations are balanced mainly by the bicarbonate anion (Fig. 8). The dominance of Ca2+ and Mg2+in the highland groundwater (see Fig. 7 and Table 1) is a result of the weathering of olivine, pyroxene and plagioclase, which are major components of basalts (GSE 2012). However, further hydrolysis along the flow path from the highland towards the rift floor through acidic volcanic rocks such as ignimbrite, pumice, tuff, ash, rhyolite and trachyte enriches the water in Na+, K+ and HCO3−, whereas the Ca2+ and Mg2+ enrichment is limited due to lack of the source rocks. The locally high relative Ca2+ and Mg2+ content in the southern part of the rift floor is mostly referred to the down faulted basaltic blocks. Beside silicate hydrolysis, cation exchange may contribute to the increase of the Na+ concentration along the flow path from the highland towards the rift floor. In addition to aforementioned geochemical processes, the chemical composition of the groundwater may be altered by mixing processes. The occurrence of thermal springs (e.g. HSP-4) and wells with high TDS values in the vicinity of cold springs (e.g. CSP-25) and shallow wells indicates the existence at least of two major groundwater flow systems in the rift floor: a shallow and a deep circulating groundwater flow system. The strong scattering of groundwater temperatures and TDS within the rift floor (Fig. 5a,b) suggests mixing of shallow and deep groundwater, e.g. at fault zones (see section ‘Hydraulic data’). Likewise, the wide range of the cation composition particularly in the shallow rift floor, which is evident from Fig. 7, may partly (besides geological heterogeneity) reflect the mixing of different flow components. The description of the hydrochemical evolution given in the preceding suggests that the deeply circulating groundwater is recharged in the upper catchment (highland and escarpment) and chemically altered along its flow path into the rift floor. Fig. 8 Relationship between major cation species and [HCO3−] content (R2 = 0.88) Groundwater isotopic composition Stable hydrogen (δ2H) and oxygen (δ18O) isotopes δ2H and δ18O values for local rainfall throughout the study area are not well documented. However, the International Atomic Energy Agency’s (IAEA) water resources programme has surveyed the stable isotopic composition of rainfall at Hagreselam station as a part of the Global Network of Isotopes in Precipitation (GNIP) for a relatively short period of time (1999–2001). Hagereselam GNIP station is located in the eastern part of the catchment at about 2,820 m a.s.l.; the mean precipitation is 1,320 mm. Based on the mean monthly rainfall isotopic data, the Hagereselam Meteoric Water Line (HMWL) δ2H = 8.42 δ18O + 16.82 (R2 = 0.96) is derived. The intercept of HMWL (16.82 ‰) is higher than that of the Global Meteoric Water Line (GMWL; 10 ‰) showing higher deuterium (d) excess. This is a very common phenomenon in the Ethiopian highland rainfalls (Sonntag et al. 1979; Joseph et al. 1992; Rozanski et al. 1996; Darling and Gizaw 2002) . Kebede (2004) and Levin et al. (2009) confirmed that the dexcess is attributed to the mixing of recycled moisture from continental source and direct moisture from the Indian Ocean. The isotopic composition of δ18O and δ2H of groundwater samples (Table 1) in the Gidabo River Basin together with HMWL is presented in Fig. 9a. It appears that the groundwater samples plot along or close to the local meteoric line, suggesting that the groundwater originated exclusively from local precipitation without an additional significant input, e.g. from a juvenile magmatic source. Although the isotopic composition of all water samples indicates meteoric origin, the Fig. 9 a The δ18O-δ2H diagram of water samples from the Gidabo River Basin. The HMWL is defined by the relation δ2H = 8.42 δ18O + 16.82, and the GMWL by δ2H = 8 δ18O + 10 (Craig 1961) . b Shallow groundwater δ18O vs. elevation. The linear trend shows an isotopic gradient of −0.15 ‰ per 100 m of elevation rise (δ18O = − 0.0015 elevation (m) + 1.58; R2 = 0.84) scattering around the meteoric water line suggests that their isotope signature is modified by evaporation and subsurface processes such as isotope exchange with the aquifer matrix. Some of the shallow groundwater samples in the center of the rift floor plot below the HMWL. This is due to evaporative isotope fractionation prior to recharge, which results in discrimination of 18O and 2H versus 16O and 1H, respectively, during the evaporation process, and thus heavier isotopes are accumulated in the remaining water (Clark and Fritz 1997) . Evaporation is a major process for water loss in the water balance of the basin; it is found to be extremely high in the rift floor (Mechal et al. 2015) and accordingly could considerably modify the isotopic signature of the respective groundwater. Likewise, some of the geothermal boreholes (BH-46 and 49) show a sign of positive 18O shift from the HMWL which might be attributed to high temperature exchange between the groundwater and the siliceous host rock (Craig 1963; Schofield and Jankowski 2004) . On the contrary, HSP-1 plots slightly above the HMWL showing a negative 18O shift, which may be related to exchange between the 18O of the waters and that of the CO2 rising through a fault, a wellknown phenomenon in extremely CO2-rich thermal waters (D’Amore and Panichi 1987). In general, evaporation is found to be the major process affecting the isotopic signature of the groundwater in the study area especially in the rift floor, whereas subsurface processes such as water–rock interaction have less influence. The isotopic signature of the groundwater samples shows a systematic spatial variability across the catchment. As depicted in Fig. 9a, the δ18O and δ2H values of the groundwater generally show enrichment from the highland towards the rift floor; however, the δ18O and δ2H of some rift floor samples and particularly of the deep circulating thermal groundwater do not fit into the enrichment trend. The mean values of δ18O and δ2H in thermal groundwater are depleted from shallow groundwater by 1.1 and 7.3 ‰, respectively, clearly showing a difference in the recharge elevation of the two systems. Assuming a conservative behavior of stable oxygen isotope (Clark and Fritz 1997) , the relationship between δ18O values and elevation (Dansgaard 1961) is established using shallow groundwater data that represent the average isotopic composition of precipitation in their immediate locality (Fig. 9b). This helps to check the recharge area of the two different groundwater systems. The observed elevation effect (−0.15 ‰/100 m) is in good agreement with the observation of Kebede and Travi (2011) in the western Ethiopian plateau and the Afar depression (−0.10 ‰/100 m). Taking into account both δ18O-elevation relationships, the average recharge elevation for the δ18O depleted thermal and deep rift floor groundwater are calculated to be 2,600 m a.s.l. This elevation belongs to the highland physiographic region, which ranges approximately from 2,400 to 3,200 m a.s.l. Therefore, the δ18O and δ2H depleted groundwater in the rift floor is deep circulating groundwater that originated from the highland and parts of the escarpment, while the rift floor aquifers are recharged from local precipitation. In other words, the rift floor aquifers are hydraulically connected to the escarpment and highland aquifers, a conclusion which is also substantiated by the results from the hydrochemical study. Thermal groundwater is highly mineralized Na–HCO3 type water generated by water–rock interaction along the flow path from the highland to the rift floor, while shallow groundwater is locally circulating Na/Ca–HCO3 type water, which compared with the thermal water is characterized by lower temperature, lower pH and lower TDS. As the aquifer system of the area is characterized by unconfined aquifers overlying semi-confined aquifers and the existence of intense fracturing (faults; Fig. 1), links between shallow and deep circulating groundwater system are assumed to exist. In order to detect the possible mixing of the two identified groundwater flow systems, δ18O versus temperature (Fig. 10) were plotted. In the absence of mixing, the thermal waters would be expected to have δ18O signatures clearly different from the colder shallow waters of the rift floor; Fig. 10 δ18O vs temperature of groundwater however, the δ18O versus temperature plot shows that although the δ18O values of the thermal groundwater tend to lower values, both thermal water and other rift floor samples scatter around the mean value of the data set. This suggests mixing between the thermal groundwater and the shallow groundwater within the rift floor. δ2H or δ18O values can be used to quantify the regionalscale mixing of groundwater of different recharge origin, aquifers and flow systems (Clark and Fritz 1997) . To estimate the percentage of the shallow groundwater contribution to the thermal groundwater system a simple two-component system was conceptualized. To simplify the calculation of the mixing proportion, it is assumed that the sampled thermal groundwater is a mixture of two end-members, a deep circulating thermal water component and a non-thermal groundwater located in the rift floor and highland. Samples that were determined to be influenced by processes other than mixing (e.g. BH-46, BH-49, HSP-1 as discussed already) were discarded. The remaining data points are focused on parts of the rift floor close to the edge of the escarpment. The mean values used for the calculation are given in Table 2. Assuming a conservative behavior of δ18O, mixing of shallow cold groundwater with thermal groundwater in the rift floor is estimated using the binary mixing equation: Shallow groundwater in the highland (n = 4) Shallow groundwater in the rift floor (n = 13) Thermal groundwater (n = 7) δ18O (‰) δ18OTS ¼ X:δ18ORSGW þ ð1−XÞ: δ18OHGW ð1Þ where δ18OTS = mixed thermal groundwater; X = volume proportion; δ18ORSGW = new water contribution from shallow groundwater in the rift floor; δ18OHGW = pre-mixing mean isotopic composition of the highland groundwater. Applying Eq. (1), a mixing ratio of 30 % is found for the shallow groundwater contribution to the thermal system. The remaining proportion is deep circulating groundwater coming from the upper catchment as indirect recharge. The mixing proportion is mostly higher near fault zones, where it amounts to nearly 50 %; away from the fault zone the mixing ratio decreases. This highlights the control which faults have on the mixing rate. As the sampling points used for this calculation are closer to the escarpment than to the rift center, the mixing proportion is assumed to decrease towards the center of the rift floor where recharge is lower (Mechal et al. 2015) . Stable carbon isotope (δ13C) The stable carbon isotopic composition of DIC from the sampled groundwater ranges from −21.7 to −1.7 ‰ (VPDB; Table 1). The highest δ13CDIC values belong to thermal groundwater in the rift floor (−5.5 to −1.7 ‰), while the lowest δ13CDIC mainly refer to groundwater sampled in the escarpment and highland (−14.5 to −21.7 ‰; Fig. 11 and Table 1). Such a wide δ13CDIC range could reflect multiple carbon sources and varying levels of geochemical evolution. The 13C isotopic composition of gaseous CO2 can be recalculated by using isotopic equilibrium fractionation according to the expression Fig. 11 Relationship of stable carbon isotopes (δ13CDIC) with [DIC] of the water δ13CCO2 ¼ δ13CCO2 þ 103 αDIC The 13C/12C fractionation coefficient between DIC and gaseous CO2 is calculated from the individual 13C/12C fractionation coefficients αf, αb, and αc at isotope equilibrium (Vogel et al. 1970; Mook et al. 1974; Thode et al. 1965; respectively) . The molar proportions xf, xb, and xc are the molar fractions for H2CO3*, HCO3−, and CO32−, respectively, obtained by hydrochemical modeling using the computer code PHREEQC (Parkhurst and Appelo 1999) with the PHREEQC database. The calculated 13C/12C composition of the CO2 gas for the dissolution of the volcanic rocks in an open system with respect to the gas phase is presented in Table 1. The upper catchment and thermal groundwater systems exhibit δ13CCO2 values from −16.6 to −4.8 and from −22.5 to −17.4 ‰ (VPDB), respectively. The DIC in groundwater may be released from four main sources having different carbon isotope signatures: (1) biogenic processes (soil respiration) with δ13C values lower than −23 ‰ (VPDB); (2) dissolved limestone (e.g. marine limestone δ13C close to 0 ‰, VPDB); (3) metamorphic processes with δ13C slightly above 0 ‰ (VPDB) and (4) mantle origin having values between −3 and −8 ‰ (VPDB; Javoy et al. 1986; Vogel 1993; Mayo and Muller 1997; Marty and Zimmermann 1999; Cartigny et al. 2001; Carreira et al. 2010; Alemayehu et al. 2011) . The stable (δ18O and δ2H) isotopic composition of groundwater in the study area reveals local meteoric origin (Fig. 9a). As water infiltrates through the soil zone, DIC is gained by dissolution of carbon dioxide gas that exists in the soil as a result of biological activity. Both C3 plants (e.g. coffee, eucalyptus tree, mango) and C4 plants (e.g. grasses, maize, sorghum), which are assumed to be the main source of soil CO2, are widely available. The δ13C of soil CO2 in most C3 landscapes is generally about −23 ‰, while that of soilhosting C4 plants is closer to about −9 ‰ (Vogel 1993) . The δ13C signature of soil CO2 in the study area is therefore assumed to be within C3 and C4 plant range (−23 ‰ to −9 ‰). Hence, it is plausible to interpret that the δ13CDIC value of shallow groundwater all over the catchment show typical soil carbon source from C3 and C4 plants, explaining in part the wide range of δ13CDIC values observed (Fig. 11). The calculated δ13CCO2 of the shallow groundwater also shows similar signature to soil carbon; however, the δ13CDIC signature of the thermal groundwater in the rift floor cannot be explained only by soil CO2. The anomalous TDS and DIC measured in the highly enriched δ13C thermal groundwater cannot be only the result of the hydrochemical evolution as the groundwater flows from the highland to the rift floor. Beside the soil CO2, there should be additional CO2 triggering the silicate hydrolysis resulting in a high TDS and DIC signature of the thermal groundwater. The stratigraphic sequence of the region shows that the basement (metamorphic) rocks are capped by a very thin layer of residual sandstone; above this layer the volcanic rocks continue to the surface (Ebinger et al. 1993) ; therefore, sedimentary rocks (limestone) are missing and cannot be the source of CO2. Considering the location of the thermal groundwater in a volcanic setting especially in the highly faulted zone of the rift floor associated with plate boundaries, mantle CO2 ascending through deep-seated faults may be reasonably assumed as the additional CO2 source, which is also suggested by δ13CCO2 range of the thermal groundwater (Table 1). Therefore, the analyzed δ13CDIC range can be interpreted by the origin of CO2 from mainly two sources: soil and mantle CO2. An additional source is also atmospheric CO2, although the amount should be very limited. Groundwater from the highland and upper escarpment which is characterized by low pH and DIC as well as depleted δ13C indicates a soil CO2 source causing less silicate weathering (Fig. 11). The exceptionally enriched δ13C value of DIC in thermal groundwater that displays the highest pH and DIC indicates the presence of mantle CO2 causing strong silicate weathering. Further evolved groundwater from the upland towards the lower escarpment and shallow rift floor area has intermediate pH, DIC and δ13C signature. These can be explained as mixtures of the two end members: soil and mantle CO2. The thermal groundwater in the rift floor displays strong variability in the groundwater composition, for instance wide ranges of TDS (225–2,320 mg/l) with parallel enrichment of δ13CDIC signature. Thermal groundwater characterized by higher TDS values and enriched in δ13CDIC (≥5.5 ‰; Fig. 11; e.g. thermal springs close Dilla town) is related to strong water– rock interaction aided by mantle CO2 coming through the deep seated faults, whereas the lower TDS values and relatively depleted δ13CDIC signature (e.g. thermal springs close to the town of Yirgalem) are linked to the evolution of groundwater along the flow path from the highland towards the rift floor. This suggests that the influx of CO2 from a mantle source through fault systems locally is a relevant process controlling the rate of water–rock interaction in the rift floor. Conceptual hydrogeological model The conceptual model of the hydrogeological system of Gidabo River Basin is presented based on the evidence obtained from geomorphological, geological, hydraulic, hydrochemical and isotopic data (Fig. 12). This multi-proxy approach provided important information to achieve the conceptual model of the groundwater circulation from the upland towards the main rift axis. The geomorphologic setting of the area is characterized by the high mountain area to the east, the single prominent rift boundary fault escarpment and the floor of the rift valley in the west. The rift valley floor comprises a series of NNE–SSW trending horst and graben structures and right stepping faults running parallel to the NE–SW trending main rift axis. Recharge mainly takes place in the mountain and upper escarpment in the order of 300–400 mm/year and gradually drops towards the center of the rift floor (25 mm/year) due to increasing evapotranspiration and decreasing rainfall rate (Mechal et al. 2015) . Interlayered weathered and fractured basalts and ignimbrites are the major aquifers in the highland and escarpment, whereas the main aquifers in the rift floor are composed of a mixture of pyroclastic flows (ignimbrite and pumice) or alluvial and lacustrine deposits. Due to the absence of a conceivable extended confining layer and severe disruption of the multi-layer aquifers by various deep-seated faults, a good hydraulic connection is assumed to exist. As the aquifer system in the area comprises unconfined aquifers overlying semi-confined aquifers, recharge occurs all over the basin. In the highland and escarpment, parts of the water recharged to the shallow aquifer system discharge to the nearby depressions along the rift boundary fault contributing to the baseflow of streams and springs, while the remaining water moves through the rocks to the deeper aquifers and joins the regional groundwater flow towards the rift floor (Fig. 12); therefore, shallow and localized groundwater flow paths are superimposed on deeper regional pathways. This is clearly seen by the progressive increase in spring discharge starting from the highland to the rift floor, suggesting that the rift boundary fault plays a major role in the occurrence of springs and the drainage of groundwater from the highland and escarpment into the rift floor aquifers. Likewise the water level map (Fig. 4) shows that groundwater flows regionally from the upland areas in the east towards the rift floor. The systematic trends of groundwater temperature, TDS, major ion concentrations and environmental isotopes (δ2H, δ18O, and δ13C) further support the existence of a hydraulic connection and groundwater movement from the highland and escarpment to the deep rift floor aquifers. The results of a highly simplified 2D groundwater model of Gidabo River Basin (Mechal et al. 2016) also suggest that the rift floor aquifers receive a significant contribution of groundwater flow from the highland and escarpment (mountain-block recharge). However, groundwater movement within the rift floor is very elusive and highly influenced by geological structures. The change in aquifer configuration and topography due to faults has substantial impact on groundwater flow and is strongly dependent on the dip direction and scale of the normal faults. Normal faults dipping to the east likely act not only as (leaky) barriers to the horizontal flow but also as conduits parallel to the fault plane, thus favoring the existence of thermal springs, wetlands and swamps (Fig. 13), whereas westward dipping faults (e.g. the rift boundary fault) are assumed to facilitate the downward movement and transfer from the highland towards Lake Abaya (Fig. 12). For instance, the discharge of exceptionally mineralized hot water near the boiling point in the thermal springs, which are highly influenced by mantle CO2 coming through the fault system, is indicative of faults acting as hydraulic conduits connecting shallow and deep circulating groundwater; the faults simultaneously act as barriers to horizontal flow across the fault. The thermal springs are concentrated along the fault line; their lateral extent can be inferred from deep geothermal boreholes with similar hydrochemical and isotopic signatures crossing through the faults (Fig. 13), which is probably related to the presence of multi-layer aquifers in which the groundwater has different options to pass through the fault zones. This is consistent with the aforementioned hypothesis that the faults in the region generally act as complex conduit leaky barrier systems in which preferential or enhanced flow along the fault plane occurs, while flow across the fault is semi-impeded. Similar hydraulic and thermal effects of fault zones were reported, e.g. by Bense et al. (2008) . To characterize the general groundwater movement within the rift floor, the area is categorized as northern and southern rift floor. The northern part of the rift floor is characterized by the WFB system. The horst-graben structures are well developed by the combination of the above fault systems together with the prominent right-stepping faults rising above 2,000 m a.s.l. in the rift floor. The water level map (Fig. 4) indicates two major flow directions within the rift floor: across the rift (E–W) and parallel to the rift (N–S). The series of eastward dipping faults are a major barrier for the groundwater coming from the upper catchment and drain parallel to sub-parallel to the axis of the rift towards Lake Abaya following the elevation gradient. The fault-induced topography (horst-graben structures) creates low-lying zones of wetlands and swamps, representing the major sinks for groundwater flow in the northern area (Fig. 12). As a result, the overall westward moving groundwater is gradually diverted towards the rift parallel flow system. This conceptual model is also supported by the hydrochemical and isotope data: In the area west of the towns Hantete and Derara (see Fig. 1) both shallow (e.g. BH-176) and deep (e.g. BH-194) groundwater are enriched in δ18O and δ2H and are only slightly mineralized (TDS < 250 mg/l), suggesting a dominance of the local recharge over the deep regional flow component, which is consistent with the aforementioned diversion of the regional groundwater flow from E–W to N–S. In contrast, in the southern and central part of the study area, the general groundwater flow is straight E–W towards Lake Abaya. This needs further investigation but might be attributed to the generally lower abundance, small throw and lateral pinching of faults in this area. Fig. 13 An example of the hydrogeological behavior of faults (e.g. Odo mike fault zone close to the town of Dilla) acting as both semi-barriers and conduits. The red arrows show the assumed groundwater flow paths in the fault zone delineated by hydrochemical data. See Fig. 12 for the location of the fault in the cross section line B–B′ Conclusion Hydrochemical and isotope data together with well head and spring discharge observations enabled characterization of the regional groundwater flow pattern and how it is influenced by the tectonic setting of the rift in the Gidabo River Basin. The techniques employed are mutually supportive and the extracte d i n f or m at i o n w a s u s e d t o d e ve l op a c on c e pt ua l hydrogeological model characterizing the flow paths to the main rift axis, advancing the general understanding of the complex hydrogeological system of the Ethiopian Rift. B o t h t h e o b s e r v e d g r o u n d w a t e r l e v e l s a n d t h e hydrochemical and isotopic composition of the groundwater indicate groundwater flow from the major recharge area in the highland and escarpment into deep rift floor aquifers. Thus, a deep regional flow system can be distinguished from the shallow local aquifers. As a result of the deep groundwater circulation and the high geothermal gradients, thermal groundwater and hot springs are found in the rift floor. Groundwater gradually evolves from slightly mineralized Ca–Mg–HCO3 type in the highland to highly mineralized Na– HCO3− type in the rift floor. The hydrochemical evolution of groundwater is largely linked to silicate hydrolysis by the uptake of gaseous CO2 gained from soil; however, locally in the rift floor, deep circulating thermal groundwater is additionally loaded with mantle CO2 coming through deep-seated faults. The influx of mantle CO2 enhances silicate hydrolysis and thus leads to a locally anomalous composition of the thermal waters with high TDS and high fluoride concentrations. Yet, unlike the central and northern MER, suffering water quality problems due to high salinity and high fluoride content, the majority of groundwater in the Gidabo River Basin displays rather diluted solutions. The δ18O and δ2H data indicate meteoric origin and little modification by evaporation and subsurface processes such as rock–water interactions and exchange with CO2 emerging from the mantle through fault systems. The spatial variability of δ18O and δ2H is controlled by the elevation of the recharge area and the mixing of local recharge and deep regional groundwater flow. The main recharge areas of the deep aquifers are located in the highland, probably around 2,600 m a.s.l. The rift floor aquifers are recharged from local precipitation and regional groundwater flow from the escarpment and highland aquifers (mountain-block recharge). A two-component mixing analysis suggests that the shallow groundwater contributes on average around 30 % to the thermal groundwater system in the rift floor. Near fault zones, the contribution of the shallow groundwater to the thermal groundwater is found to be higher. Groundwater movement within the rift floor is complex and highly constrained by geological structures. Normal faults dipping to the west appear to facilitate movement of groundwater into deeper aquifers and towards the rift floor, whereas those dipping to the east tend to act as leaky barriers perpendicular to the fault but enable preferential flow parallel to the fault plane. As a result, the series of horst graben structures together with the prominent right-stepping faults are major barriers and sinks for the local groundwater circulation in the northern rift floor. Groundwater coming E–W from the upland is diverted and drained parallel to sub-parallel (N–S) to the axis of the rift towards Lake Abaya. In contrast, the general groundwater flow in the southern and central part of the rift floor is straight E–W towards Lake Abaya. Further local investigations will be needed to obtain a more detailed understanding of the hydraulic functioning of the individual fault zones and their influence on the groundwater flow pattern within the rift. Acknowledgements Open access funding provided by University of Graz. The Austrian Partnership Programme in Higher Education and Research for Development (APPEAR) is acknowledged for a PhD research grant to the first author. Sidama, Gedeo and Borena zone water resources development offices are warmly thanked for their guidance during the field work and delivering well completion reports. Hydrochemical and isotope analyses were conducted at NAWI Graz Central Lab for Water, Minerals and Rocks, Johanneum Research, Institute of Water, Energy and Sustainability and Addis Ababa University, school of Earth Science. The authors acknowledge A. Baldermann, J. 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Abraham Mechal, Steffen Birk, Martin Dietzel, Albrecht Leis, Gerfried Winkler, Aberra Mogessie, Seifu Kebede. Groundwater flow dynamics in the complex aquifer system of Gidabo River Basin (Ethiopian Rift): a multi-proxy approach, Hydrogeology Journal, 2017, 519-538, DOI: 10.1007/s10040-016-1489-5