Preparation of Nickel Ferrite/Carbon Nanotubes Composite by Microwave Irradiation Technique for Use as Catalyst in Photo-Fenton Reaction

Materials Research, Feb 2019

Caroline Rigo, Eric da Cruz Severo, Marcio Antonio Mazutti, Guilherme Luiz Dotto, Sérgio Luiz Jahn, André Gündel, Márcia Maria Lucchese, Osvaldo Chiavone-Filho, Edson Luiz Foletto

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Preparation of Nickel Ferrite/Carbon Nanotubes Composite by Microwave Irradiation Technique for Use as Catalyst in Photo-Fenton Reaction

Articles Preparation of Nickel Ferrite/Carbon Nanotubes Composite by Microwave Irradiation Technique for Use as Catalyst in Photo-Fenton Reaction Caroline Rigoa  Eric da Cruz Severoa  Marcio Antonio Mazuttia  Guilherme Luiz Dottoa  Sérgio Luiz Jahna  André Gündelb  Márcia Maria Luccheseb  Osvaldo Chiavone-Filhoc  Edson Luiz Folettoa  *  aDepartment of Chemical Engineering, Universidade Federal de Santa Maria, 97105-900, Santa Maria, RS, Brazil bUniversidade Federal do Pampa, 96413-170, Bagé, RS, Brazil cDepartment of Chemical Engineering, Universidade Federal do Rio Grande do Norte, 59066-800, Natal, RN, Brazil ABSTRACT Nickel ferrite/multi-walled carbon nanotubes (NiFe2O4/MWCNTs) composite has been rapidly synthesized via microwave irradiation technique. The structural properties of the product was investigated by X-ray diffraction (XRD), N2 adsorption/desorption isotherms, thermogravimetric analysis (TGA), Raman spectroscopy and, scanning electron microscopy (SEM). Catalytic behavior of the composite material on the advanced photo-Fenton degradation of Amaranth dye was evaluated. The synthesis conditions employed on the microwave system were: temperature (235 °C), power (500 W), pressure (600 psi) and irradiation time (30 min). Characterization results showed the formation of hybrid material, containing a predominantly microporous structure, with surface area and total pore volume of 54 m2 g-1 and 0.2249 cm3 g-1, respectively. The composite exhibited higher catalytic activity compared to the pure NiFe2O4, reaching 100% of decolorization at 60 min of reaction, which can be attributed to a synergism between NiFe2O4 and MWCNTs. Therefore, NiFe2O4/MWCNTs composite can be used as a promising photo-Fenton catalyst to degrade Amaranth dye from aqueous solutions. Keywords: Multi-walled carbon nanotubes; nickel ferrite; composite; photo-Fenton 1. Introduction Advanced oxidation processes (AOPs) are alternative emerging techniques for the degradation of organic pollutants in wastewater1-6. AOPs are divided in a variety of methods, and among them, heterogeneous Fenton reaction is one of the most interests, which to use iron-based solid catalyst, whose major advantage is its easy recovery from the solution by a field magnetic for further reutilization7-9. In the presence of a light source, known as photo-Fenton reaction, the pollutant degradation rate substantially increases10,11. The photo-Fenton process applies the combination of hydrogen peroxide, iron ions and light irradiation in an acidic aqueous medium (pH ≤ 3)12, producing highly oxidative radicals (HO•)10, leading to degradation of pollutant molecules. Therefore, a simplified mechanism for the heterogeneous photo-Fenton degradation of organic pollutant under light irradiation can be depicted as follows (Equations 1-3): ≡FeIII+H2O2+lightirradiation→≡FeII+HO2•+H+ (1) ≡FeII+H2O2+lightirradiation→≡FeIII+HO•+H− (2) Organicpollutant+HO•→degradationproductsCO2+H2O+intermediates (3) where, ≡ FeIII and ≡ FeII corresponds to iron species on the surface of a heterogeneous catalyst. Recently, coupling of multi-walled carbon nanotubes (MWCNTs) with ferrite have been reported as a potential catalyst for degradation of organic pollutant. This coupling may favor the separation of electron-hole pairs on the catalyst, avoiding their recombination and generating more oxidative radicals (HO•), leading to a high catalytic performance13. Several ferrite/carbon nanotubes composites have been used for different applications14-19, but very few them have been used for application in OAPs13,20-23. Recently, nickel ferrite (NiFe2O4)/carbon nanotubes (MWCNTs) composite has been prepared via a conventional route using teflon-lined stainless autoclave at 180 ºC for 20 h, being applied as photocatalyst for the degradation of phenol under UV irradiation13. NiFe2O4/MWCNTs hybrids were prepared via one-step hydrothermal method at 180 ºC for 20 h, and their photocatalytic activity was investigated for the decolorization of Congo Red dye in aqueous solution under simulated solar light irradiation23. However, no work has yet been developed using NiFe2O4/MWCNTs composite prepared via microwave route for application as a photo-Fenton catalyst under visible light irradiation. It is well known that the use of microwave route for the preparation of powdered catalysts presents as great advantages short synthesis time and production of high surface area particles, being this last characteristic of great importance for catalytic purposes24,25. NiFe2O4 is a cubic oxide with a typical inverse spinel structure and has attracted much interest because of its fascinating magnetic and electromagnetic properties26, while the MWCNTs have attracted increasing research interest as dye adsorbent27, support for enzyme immobilization28 and catalyst support29. In this work, nickel ferrite (NiFe2O4)/carbon nanotubes (MWCNTs) composite was prepared via a rapid alternative method (microwave route) for application as catalyst on degradation of amaranth dye using heterogeneous photo-Fenton process under visible light irradiation. 2. Materials and Methods 2.1 Materials, procedures and characterization techniques Multi-walled carbon nanotubes (MWNTs-COOH functionalized) (Purity ˃ 95 wt%, outside diameter: 10-20 nm, inside diameter: 5-10 nm, Length: 10-30 mm) were purchased from Nanostructured & Amorphous Materials, Inc., USA. Amaranth dye (CAS number: 915-67-3; chemical formula: C20H11N2Na3O10S3; molecular weight: 604.47 g mol-1) was used as a model pollutant. Nickel nitrate [Ni(NO3)2.6H2O], iron nitrate [Fe(NO3)3.9H2O] and anhydrous ethyl alcohol were utilized without any further treatment. A modified procedure for the preparation of NiFe2O4/MWCNTs composite was employed in this work, which was based on a previously reported work13, where a hydrothermal conventional method has been employed for the synthesis process13. From hydrothermal route, 20 h of reaction time has been necessary for the production of the respective composite13. Therefore, this present work aims to use microwave irradiation as heat source in order to accelerate the formation of material. For the obtaining the composite sample containing 25 wt% of MWCNTs, nickel nitrate (1.45 g) and iron nitrate (4.04 g) were firstly dissolved in 100 mL of ethyl alcohol. Then, 0.40 g of MWCNTs was dispersed in 600 mL of ethyl alcohol. After, the ethyl alcohol/MWCNTs suspension was added into the saline solution under stirring for 30 min at room temperature (25 ºC). This suspension was adjusted to a pH value of 14 using 10 M NaOH solution, and kept under stirring for 15 min. Then, 100 ml of deionized water was added to previous suspension, and kept under vigorous stirring for 30 min. Posteriorly, the final suspension was transferred to several high-pressure reaction vessels and submitted to microwave irradiation (MARS 6 Microwave equipment, ESP 1500 plus, USA), under the following conditions: temperature (235 °C), power (500 W), pressure (600 psi) and irradiation time (30 min). The obtained composite was collected and washed with deionized water for several times, and then, dried at 110 ºC for 12 h. For comparison purposes of the catalytic activity, pure NiFe2O4 particles were prepared using the same previous mentioned procedure without the addition of MWCNTs. The concentration of free Fe ions in the solution after irradiation was measured by atomic absorption spectroscopy (Agilent Technologies, 200 series AA) to monitor their leaching from the catalysts. Characterization of the materials was identified using an X-ray diffractometer (Rigaku Miniflex 300), with Cu-Kα radiation, powered at 30 kV and 10 mA. Scans were performed over 2θ angles ranging from 15 to 65º. Thermogravimetric analysis was carried out on a TGA-50 Shimadzu analyzer at a heating rate of 10 ºC min-1 in presence of an air flow rate of 50 mL min-1, in the temperature range from 25 to 900 °C. Nitrogen adsorption-desorption isotherms were obtained at 77 K carried out on an ASAP 2020 apparatus at relative pressure (P/P0) ranging from 0 to 0.99. Specific surface areas were calculated according to the Brunauer-Emmett-Teller (BET) method and, the pore-size distributions were obtained according to the Barret-Joyner-Halenda (BJH) method. Raman spectroscopy measurements were performed at room temperature using a micro-positioning system B&WTek and an Andor Shamrock 303i monochromator. The morphology of the composite was examined by a scanning electron microscope (SEM, JEOL JSM-6610LV) at 15 kV, and its chemical composition was obtained by energy dispersive X-ray spectroscopy (EDS), which is coupled to the SEM equipment. 2.2 Photo-Fenton experiment For the degradation tests of 50 mL Amaranth dye solution at room temperature (50 mg L-1) and pH 2.5 (adjusted using 0.1 M H2SO4), the catalyst amount (NiFe2O4 and NiFe2O4/MWCNTs composite) used was 0.05 g and the H2O2 (30% v/v) volume was 50 µL. Prior to illumination, the aqueous suspension containing catalyst and dye was magnetically stirred in the dark until to achieve the adsorption equilibrium. In order to avoid adherence of the magnetic catalyst on the magnetic bar, a vigorous agitation (150 rpm) was employed. It was found that an agitation rate above this value is adequate for to obtain a homogeneous suspension during the stirring step. Then the suspension was exposed to visible light irradiation under stirring. The visible-light source was commercial fluorescent lamp (85 W, Empalux) positioned 10 cm above the liquid surface. Samples were taken at set intervals using a syringe and, filtered immediately through a PVDF membrane (0.45 µm). The dye concentration in the filtered suspension was determined by the absorbance reading on an UV-vis spectrophotometer (Shimadzu, UV-2600), at a maximum absorption wavelength of 520 nm. 3. Results and Discussion XRD diffraction patterns of MWCNTs, pure NiFe2O4 and NiFe2O4/MWCNTs composite are shown in Figure 1. The major peaks corresponding to the planes (0 0 2) and (1 0 1) at 2θ positions of 26.5 and 43.4º are characteristic peaks of MWCNTs30 (Figure 1a). In Figure 1b, the peaks located at 18.4, 30.3, 35.7, 37.3, 43.3, 53.8, 57.3, and 63.0° can be indexed to the (111), (220), (311), (222), (400), (422), (511) and (440) crystal planes of NiFe2O4 spinel, respectively, according to the JCPDS Card No. 54-0964 (Bars inset to Figure 1 correspond to reference NiFe2O4). From Figure 1c, the presence of the peak to 26.5° (which corresponds to MWCNTs material) on the XRD pattern of the NiFe2O4/MWCNTs composite, indicates the successful formation of respective hybrid material. Figure 1 X-ray diffractograms of (a) MWCNTs, (b) pure NiFe2O4 and, (c) NiFe2O4/MWCNTs composite. Bars inset correspond to reference NiFe2O4, according to the JCPDS Card No. 54-0964.  Raman spectra of MWNTs, NiFe2O4/MWNTs composite and pure NiFe2O4 are shown in Figure 2. The peaks at 1350 cm-1 (band D) and 1580 cm-1 (band D) are typical of MWCNTs31 (Figure 2a), while the peaks to 470 cm-1 and 690 cm-1 correspond to typical peaks of NiFe2O432 (Figure 2b). All peaks above mentioned are presents on the Raman spectrum of the NiFe2O4/MWCNTs composite (Figure 2c), demonstrating the successful preparation of the NiFe2O4/MWNTs hybrid composite. Figure 2 Raman spectra of (a) MWCNTs, (b) pure NiFe2O4 and, (c) NiFe2O4/MWCNTs composite.  Thermogravimetric analysis (TGA) was used to evaluate the amount of MWCNTs incorporated on the prepared NiFe2O4/MWCNTs composite. Figure 3 shows the TGA of the pure NiFe2O4 (Figure 3a), NiFe2O4/MWCNTs composite (Figure 3b) and MWCNTs (Figure 3c). According to Figure 3, the MWCNTs have total mass loss at 800 °C (Figure 3c), while the pure NiFe2O4 remains stable up to 900 °C (Figure 3a). From Figure 3b, it is possible to observe a mass loss about 25%, corresponding to thermal oxidation of MWNTs presents in the NiFe2O4/MWCNTs composite. This result indicates that the procedure used in this work for the composite preparation was done successfully. Figure 3 Thermogravimetric analysis of (a) pure NiFe2O4, (b) NiFe2O4/MWCNTs composite, and (c) MWCNTs.  Representation of the nitrogen adsorption-desorption isotherms and pore-size distributions for MWCNTs, pure NiFe2O4 and NiFe2O4/MWCNTs samples are shown in Figure 4. The isotherms for the all the samples shown in Figure 4a are similar and can be classified as type II. The shape of these isotherms indicates that all the samples possess predominantly microporous structure. In addition, the microporous structure was confirmed by the analysis of pore-size distribution (Figure 4b), which shows spectra of pore-size distributed on the microporous region (pore-size less than 2 nm). Pore properties of the samples are shown in Table 1. Values of surface area and total pore volume of NiFe2O4/MWCNTs composite are between those of MWCNTs and pure NiFe2O4. Figure 4 (a) Nitrogen adsorption/desorption isotherms of MWCNTs, NiFe2O4/MWCNTs and NiFe2O4 and, their (b) pore-size distributions.  Table 1 Pore properties of the samples.  Sample Surface area (m2 g-1) Total pore volume (cm3 g-1) NiFe2O4 32 0.1684 MWCNTs 103 0.4881 NiFe2O4/MWCNTs 54 0.2249 Figure 5 shows SEM images of NiFe2O4/MWCNTs composite (Figures (5a) and (5b) under different magnifications), NiFe2O4 (Figure (5c)) and MWCNTs (Figure (5d)). In Figure (5e), it is showed the chemical composition of composite obtained from EDS analysis. Particles with irregular shape can be observed on the respective images of the composite (Figure (5a)) and NiFe2O4 (Figure (5c)), whereas nanotubes well adhered on the surface of the NiFe2O4 particle can be observed in Figure (5b). In addition, it is possible to observe that the nanotubes maintained their morphology after the microwave process. From Figure (5e), it was found an atomic ratio of 1:2 (Ni:Fe), which confirms the formation of NiFe2O4 spinel. Figure 5 SEM images of NiFe2O4/MWCNTs composite [Magnification: 500 X (a); 20,000 X (b)], NiFe2O4 (Magnification: 500 X) (c) and MWCNTs (Magnification: 20,000 X) (d), and EDS analysis (e) of NiFe2O4/MWCNTs composite.  Preliminary tests on the presence of catalyst in the dark without H2O2 (catalyst/dark), without catalyst (H2O2/light) and without H2O2 (catalyst/light) showed negligible decolorization results, whereas the Fenton process (catalyst/H2O2/dark) exhibited about 7.0% of decolorization at 60 min of reaction time. Therefore, the effective dye degradation is attributed to the synergetic effect of the combination among catalyst/H2O2/visible light (photo-Fenton process). As shown in Figure 6, the linear relationship of C/C0 versus reaction time shows that the dye decolorization via photo-Fenton process followed the zero-order kinetics3,8,33 for both the catalysts. The slopes of lines correspond to the reaction rate constants (k composite = 0.017 mg L-1 min-1 and kferrite = 0.001 mg L-1 min-1). This result indicates that the composite shows higher activity compared to pure ferrite. The dye was substantially degraded from the aqueous solution, reaching 100% at 60 min of reaction time. On the other hand, 60% of decolorization was obtained at 60 min using pure ferrite. The significant enhancement in catalytic activity by the NiFe2O4/MWCNTs composite can be attributed to the synergistic effect between NiFe2O4 and MWNTs that reduce the rate of recombination of photoinduced electrons and holes, leading to high catalytic performance13,30. In addition, the higher surface area and pore volume of NiFe2O4/MWCNTs composite compared to the pure NiFe2O4 could offer a larger contact and diffusion of dye molecules within the pores of its particles, contributing to the close contact between the HO• radicals and dye molecules, which leads to an increasing reaction rate. Figure 6 Catalytic activity of NiFe2O4 and NiFe2O4/MWCNTs for the degradation of Amaranth dye by photo-Fenton process.  From leaching essays for both the catalysts, very low amount of Fe (about 2 mg L-1) was detected by atomic absorption spectroscopy in the solution after 60 min of irradiation, indicating that the dye degradation was due to the heterogeneous Fenton reaction. According to Brazilian environmental legislation (CONAMA)34, a maximum of 15 mgFe L-1 is allowed for discharge into a body of water. Therefore, this result indicates a good stability of the catalyst in photo-Fenton reaction. 4. Conclusions NiFe2O4/MWCNTs composite was successfully prepared using microwave irradiation technique. The studies showed the formation of single phase particles of NiFe2O4 on the composite. Hybrid material with surface area and total pore volume of 54 m2 g-1 and 0.2249 cm3 g-1, respectively, was obtained using a microwave irradiation time of 30 min. NiFe2O4/MWCNTs composite was found to be a more efficient catalyst than the pure NiFe2O4 for the Amaranth degradation by the photo-Fenton reaction under visible light, reaching total degradation at 60 min of reaction time. Therefore, the combined effect between NiFe2O4 and MWNTs promoted a significant improvement in catalytic activity. The results indicated that the NiFe2O4/MWCNTs composite could be employed as an efficient catalyst for the treatment of dye-containing wastewater. 5. Acknowledgements The authors would like to thank to FAPERGS (Foundation for Research of the State of Rio Grande do Sul/Brazil) by the scholarship for the author C. R. 6. References 1 Ribeiro PC, Costa ACFM, Kiminami RHGA, Sasaki JM, Lira HL. Synthesis of TiO2 by the pechini method and photocatalytic degradation of methyl red. Materials Research. 2013;16(2):468-472. DOI: 10.1590/S1516-14392012005000176 [ Links ] 2 Luna AJ, Nascimento CAO, Foletto EL, Moraes JEF, Chiavone-Filho O. Photo-Fenton degradation of phenol, 2,4-dichlorophenoxyacetic acid and 2,4-dichlorophenol mixture in saline solution using a falling-film solar reactor. Environmental Technology. 2014;35(3):364-371. DOI: 10.1080/09593330.2013.828762 [ Links ] 3 Battiston S, Rigo, Severo EC, Mazutti MA, Kuhn RC, Gündel A, et al. Synthesis of zinc aluminate (ZnAl2O4) spinel and its application as photocatalyst. Materials Research. 2014;17(3):734-738. DOI: 10.1590/S1516-14392014005000073 [ Links ] 4 Kehinde F, Aziz HA. Textile waste water and the advanced oxidative treatment process, an overview. International Journal of Innovative Research in Science, Engineering and Technology. 2014;3(8):15310-15317. DOI: 10.15680/IJIRSET.2014.0308034 [ Links ] 5 Filippo E, Carlucci C, Capodilupo AL, Perulli P, Conciauro F, Corrente GA, et al. Enhanced Photocatalytic Activity of Pure Anatase TiO2 and Pt-TiO2 Nanoparticles Synthesized by Green Microwave Assisted Route. Materials Research. 2015;18(3):473-481. DOI: 10.1590/1516-1439.301914 [ Links ] 6 Silva SS, Chiavone-Filho O, Barros Neto EL, Foletto EL. Oil removal from produced water by conjugation of flotation and photo-Fenton processes. Journal of Environmental Management. 2015;147:257-263. DOI: 10.1016/j.jenvman.2014.08.021 [ Links ] 7 Baldissera MR, Silva MRA, Silveira CA, Lima RM, Maia SA, Silva MR, et al. Synthesis and characterization of Zn and Mn ferrites from spent batteries. Cerâmica. 2014;60(353):52-56. DOI: 10.1590/S0366-69132014000100007 [ Links ] 8 Severo EC, Anchieta CG, Foletto VS, Kuhn RC, Collazzo GC, Mazutti MA et al. Degradation of Amaranth azo dye in water by heterogeneous photo-Fenton process using FeWO4 catalyst prepared by microwave irradiation. Water Science and Technology. 2016;73(1):88-94. DOI: 10.2166/wst.2015.469 [ Links ] 9 Anchieta CG, Dotto GL, Mazutti MA, Kuhn RC, Collazzo GC, Chiavone-Filho O, et al. Statistical optimization of Reactive Red 141 removal by heterogeneous photo-Fenton reaction using ZnFe2O4 oxide prepared by microwave irradiation. Desalination and Water Treatment. 2016;57(33):15603-15611. DOI: 10.1080/19443994.2015.1070761 [ Links ] 10 Pignatello JJ. Dark and photoassisted iron(3+)-catalyzed degradation of chlorophenoxy herbicides by hydrogen peroxide. Environmental Science and Technology. 1992;26(5):944-951. DOI: 10.1021/es00029a012 [ Links ] 11 Soon AN, Hameed BH. Degradation of Acid Blue 29 in visible light radiation using iron modified mesoporous silica as heterogeneous Photo-Fenton catalyst. Applied Catalysis A: General. 2013;450:96-105. DOI: 10.1016/j.apcata.2012.10.025 [ Links ] 12 Mota ALN, Chiavone-Filho O, Silva SS, Foletto EL, Moraes JEF, Nascimento CAO. Application of artificial neural network for modeling of phenol mineralization by photo-Fenton process using a multi-lamp reactor. Water Science and Technology. 2014;69(4):768-774. DOI: 10.2166/wst.2013.731 [ Links ] 13 Xiong P, Fu Y, Wang L, Wang X. Multi-walled carbon nanotubes supported nickel ferrite: A magnetically recyclable photocatalyst with high photocatalytic activity on degradation of phenols. Chemical Engineering Journal. 2012;195-196:149-157. DOI: 10.1016/j.cej.2012.05.007 [ Links ] 14 Gabal MA, Al-Harthy EA, Angari YMA, Salam MA. MWCNTs decorated with Mn0.8Zn0.2Fe2O4 nanoparticles for removal of crystal-violet dye from aqueous solutions. Chemical Engineering Journal. 2014;255:156-164. DOI: 10.1016/j.cej.2014.06.019 [ Links ] 15 Sun C, Liu Y, Ding W, Gou Y, Xu K, Xia G, et al. Synthesis and Characterization of Superparamagnetic CoFe2O4/MWCNT hybrids for Tumor-Targeted Therapy. Journal of Nanoscience and Nanotechnology. 2013;13(1):236-41. DOI: 10.1166/jnn.2013.6711 [ Links ] 16 Ensafi AA, Allafchian AR. Multiwall carbon nanotubes decorated with NiFe2O4 magnetic nanoparticles, a new catalyst for voltammetric determination of cefixime. Colloids and Surfaces B: Biointerfaces. 2013;102:687-693. DOI: 10.1016/j.colsurfb.2012.09.037 [ Links ] 17 Farghali AA, Bahgat M, El Rouby WMA, Khedr MH. Decoration of MWCNTs with CoFe2O4 Nanoparticles for Methylene Blue Dye Adsorption. Journal of Solution Chemistry. 2012;41(12):2209-2225. DOI: 10.1007/s10953-012-9934-0 [ Links ] 18 Wang W, Li Q, Chang C. Effect of MWCNTs content on the magnetic and wave absorbing properties of ferrite-MWCNTs composites. Synthetic Metals. 2011;161(1-2):44-50. DOI: 10.1016/j.synthmet.2010.10.032 [ Links ] 19 Zhang Y, Zhu M, Zhang Q, Yu H, Li Y, Wang H. Solvothermal one-step synthesis of MWCNTs/Ni0.5Zn0.5Fe2O4 magnetic composites. Journal of Magnetism and Magnetic Materials. 2010;322(14):2006-2009. DOI: 10.1016/j.jmmm.2010.01.023 [ Links ] 20 Singh C, Bansal S, Singhal S. Synthesis of Zn1-xCoxFe2O4/MWCNTs nanocomposites using reverse micelle method: Investigation of their structural, magnetic, electrical, optical and photocatalytic properties. Physica B: Condensed Matter. 2014;444:70-76. DOI: 10.1016/j.physb.2014.03.033 [ Links ] 21 Singhal S, Sharma R, Singh C, Bansal S. Enhanced Photocatalytic Degradation of Methylene Blue Using ZnFe2O4/MWCNT Composite Synthesized by Hydrothermal Method. Indian Journal of Materials Science. 2013;2013:356025. DOI: 10.1155/2013/356025 [ Links ] 22 Chen CH, Liang YH, Zhang WD. ZnFe2O4/MWCNTs composite with enhanced photocatalytic activity under visible-light irradiation. Journal of Alloys and Compounds. 2010;501(1):168-172. DOI: 10.1016/j.jallcom.2010.04.072 [ Links ] 23 Zhu HY, Jiang R, Huang SH, Yao J, Fu FQ, Li JB. Novel magnetic NiFe2O4/multi-walled carbon nanotubes hybrids: Facile synthesis, characterization, and application to the treatment of dyeing wastewater. Ceramics International. 2015;41(9 Pt B):11625-11631. DOI: 10.1016/j.ceramint.2015.05.122 [ Links ] 24 Foletto EL, Simões JM, Mazutti MA, Jahn SL, Muller EI, Pereira LSF, et al. Application of Zn2SnO4 photocatalyst prepared by microwave-assisted hydrothermal route in the degradation of organic pollutant under sunlight. Ceramics International. 2013;39(4):4569-4574. DOI: 10.1016/j.ceramint.2012.11.053 [ Links ] 25 Zawadzki M. Synthesis of nanosized and microporous zinc aluminate spinel by microwave assisted hydrothermal method (microwave-hydrothermal synthesis of ZnAl2O4). Solid State Sciences. 2006;8(1):14-18. DOI: 10.1016/j.solidstatesciences.2005.08.006 [ Links ] 26 Zabotto FL, Gualdi AJ, Eiras JA, Oliveira AJA, Garcia D. Influence of the Sintering Temperature on the Magnetic and Electric Properties of NiFe2o4 Ferrites. Materials Research. 2012;15(3):428-433. DOI: 10.1590/S1516-14392012005000043 [ Links ] 27 Machado FM, Bergmann CP, Lima EC, Adebayo MA, Fagan SB. Adsorption of a Textile Dye from Aqueous Solutions by Carbon Nanotubes. Materials Research. 2014;17(Suppl. 1):153-160. DOI: 10.1590/S1516-14392013005000204 [ Links ] 28 Garlet TB, Weber CT, Klaic R, Foletto EL, Jahn SL, Mazutti MA, et al. Carbon Nanotubes as Supports for Inulinase Immobilization. Molecules. 2014;19(9):14615-14624. DOI: 10.3390/molecules190914615 [ Links ] 29 Woan K, Pyrgiotakis G, Sigmund W. Photocatalytic Carbon Nanotube-TiO2 Composites. Advanced Materials. 2009;21(21):2233-2239. DOI: 10.1002/adma.200802738 [ Links ] 30 Dalt SD, Alves AK, Bergmann CP. Photocatalytic degradation of methyl orange dye in water solutions in the presence of MWCNT/TiO2 composites. Materials Research Bulletin. 2013;48(5):1845-1850. DOI: 10.1016/j.materresbull.2013.01.022 [ Links ] 31 Nuernberg GB, Foletto EL, Probst LFD, Carreño NLV, Moreira MA. MgAl2O4 spinel particles prepared by metal-chitosan complexation route and used as catalyst support for direct decomposition of methane. Journal of Molecular Catalysis A: Chemical. 2013;370:22-27. DOI: 10.1016/j.molcata.2012.12.007 [ Links ] 32 Jacob J, Khadar MA. Investigation of mixed spinel structure of nanostructured nickel ferrite. Journal of Applied Physics. 2010;107(11):114310-114319. DOI: 10.1063/1.3429202 [ Links ] 33 Foletto EL, Battiston S, Simões JM, Bassaco MM, Pereira LSF, Flores EMM, et al. Synthesis of ZnAl2O4 nanoparticles by different routes and the effect of its pore size on the photocatalytic process. Microporous and Mesoporous Materials. 2012;163:29-33. DOI: 10.1016/j.micromeso.2012.06.039 [ Links ] 34 CONAMA - National Council on Environment, Brazil. Available from: <http://www.mma.gov.br/port/Conama>. Access in: 4/7/2017. [ Links ] Received: September 15, 2016; Revised: July 04, 2017; Accepted: July 07, 2017 * e-mail:  This is an Open Access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


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Caroline Rigo, Eric da Cruz Severo, Marcio Antonio Mazutti, Guilherme Luiz Dotto, Sérgio Luiz Jahn, André Gündel, Márcia Maria Lucchese, Osvaldo Chiavone-Filho, Edson Luiz Foletto. Preparation of Nickel Ferrite/Carbon Nanotubes Composite by Microwave Irradiation Technique for Use as Catalyst in Photo-Fenton Reaction, Materials Research, 311-316, DOI: 10.1590/1980-5373-mr-2016-0672