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Search: authors:"Bronisław Jańczuk"

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Adsorption and Aggregation Properties of Some Polysorbates at Different Temperatures

Measurements of the surface tension of aqueous solutions of polysorbates (Tween 20, Tween 60 and Tween 80) at 293, 303 and 313 K were made. On the basis of the obtained results the Gibbs surface excess concentration of the Tweens at the water–air interface and critical micelle concentrations were determined. Knowing the Gibbs surface excess concentration and taking into account...

Composition of Surface Layer at the Water–Air Interface and Micelles of Triton X-100 + Rhamnolipid Mixtures

Measurements of the surface tensions, densities and viscosities of aqueous solutions of Triton X-100 (TX-100) and rhamnolipid (RL) mixtures, at constant concentration of RL or TX-100, were carried out. The measured values of the surface tension were compared to those determined using different theoretical models and on the basis of the surface tension of aqueous solutions of...

Adsorption and Aggregation Activity of Sodium Dodecyl Sulfate and Rhamnolipid Mixture

Measurements of the surface tension, density and viscosity of sodium dodecyl sulfate (SDS) and rhamnolipid (RL) mixtures were carried out in aqueous solution. From the obtained results, composition of mixed surface layer at the water–air interface, mixed micelles, parameter of intermolecular interactions, activity of SDS and RL in the surface layer and micelles, Gibbs standard...

Adsorption of Triton X-100 and cetyltrimethylammonium bromide mixture with ethanol at nylon-6–solution interface with regard to nylon-6 wettability: II. Work of adhesion and activity of surfactants at interfaces

On the basis of the values of the surface tension of the aqueous solutions of the Triton X-100 and CTAB mixture with ethanol, the surface tension of nylon-6 and the nylon-6–solution interfacial tension, the activity of the surfactant mixture and ethanol at the nylon-6–solution interface was calculated and compared to that at the solution–air one. For these calculations, the Sprow...

Adsorption of Triton X-100 and cetyltrimethylammonium bromide mixture with ethanol at nylon-6–solution interface with regard to nylon-6 wettability: I. The effect of adsorption on critical surface tension of nylon-6 wetting

The contact angle measurements of the aqueous solutions of p-(1,1,3,3-tetramethylbutyl)phenoxypoly(ethylene glycol) (TX-100) and cetyltrimethylammonium bromide (CTAB) mixture with ethanol on nylon-6 were made in the range of the total concentration of CTAB and TX-100 mixture from 1 × 10−6 to 1 × 10−3 M and ethanol from 0 to 17.13 M. In the CTAB and TX-100 mixture the mole...

Volumetric and Surface Properties of Short Chain Alcohols in Aqueous Solution–Air Systems at 293 K

From measurements of the surface tension, density, viscosity and light scattering of aqueous solutions of methanol, ethanol and propanol at 293 K, their activity in the surface monolayer, surface excess concentration, and apparent and partial molar volume were determined. The surface excess concentration of alcohols at the water–air interface was determined from the Gibbs...