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Search: authors:"Michiya Fujita"

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Thermal and kinetic analyses on Michael addition reaction of acrylic acid

The purpose of this study is to obtain a better understanding of Michael addition reaction (MAR) which may induce runaway polymerization of acrylic acid. The heat of MAR was measured using a C80 Calvet-type heat flux calorimeter, and products of MAR were revealed by gel permeation chromatography. The reaction rate constant of MAR was obtained from kinetic analysis. In high...