Development of active electrocatalyst for CO2 reduction to useful chemicals would be essential factor to achieve the carbon neutral society. The Co poly-4-vinyl-pyridine (P4VPy)/Ketjenblack (KB) activated thermally was found for an active electrocatalyst in the electroreduction of CO2 with water by the solid-polymer-electrolyte, SPE, electrolysis cell. Various carbon supports...
This study presents the synthesis and characterization of a novel electrocatalyst based on cobalt (II)-tetra aminophenyl porphyrin (CoTAPor) conjugated non-covalently with an iron (III) oxide-reduced graphene oxide (Fe2O3rGO). The synthesized materials were then used to modify a glassy carbon electrode (GCE), with CoTAPor-Fe2O3rGO identified as the superior electrocatalyst. The...
The efficiency of photoelectrochemical (PEC) water splitting is considerably controlled by the recombination of photogenerated electron/hole charge carriers at the interface. Herein, the correlation between composition and photoelectrochemical activity is studied by utilizing molybdenum-modified tungsten oxide electrodes. Molybdenum tungsten mixed oxides (MoxW1−xO3) were...
Miltefosine is an alkyllylosophospholipid analogue used to treat visceral leishmaniasis. Recently, reports have been made of suspected counterfeit miltefosine on the Indian market. With the risk counterfeit drugs pose to drug resistance development, quality control of antileishmanial drugs has become important. Hence, in this study, amino-functionalized multi-walled carbon...
Enhancement of the oxygen reduction reaction (ORR) activity is an important subject for the development of fuel cells. In this study, we prepared the n(111)-(111) series of Pt3Co single crystal electrodes using an induction heating furnace and investigated the ORR in 0.1 M HClO4 using the rotation disk electrode (RDE). The specific activity of the ORR (jk) increased monotonously...
Methanol has potential to replace conventional fuels. But its popularity is hindered by lower kinetics of electrode reactions, lower surface area, CO poisoning of catalysts, and higher cost of platinum-based catalysts. It is rare to find electrocatalysts for methanol oxidation in acidic media because its mechanism is not fully understood yet. In this research, HNO3 exfoliated...
In this work, we proposed a novel 3D-printed manufactured electrode system. A project was developed and optimized, compatible with commercially available potetiostats. Additive manufacturing included the modification of the pseudo-reference electrode by electrodeposition of silver and its subsequent oxidation to the Ag/AgCl form. Then the system was tested using electrochemical...
Preliminary experiments are reported to show quantitatively that hydrogen gas can be stored under triphasic conditions in wet nanoparticulate polymer of intrinsic microporosity (PIM-1) applied as a film to a platinum disk electrode surface. Based on chronoamperometric data, it is shown that the resulting triphasic interface is able to store hydrogen gas at apparent concentrations...
In recent years, the development of highly sensitive and selective electrochemical sensors has been a pivotal area of research, driven by the growing demand for environmental monitoring and industrial process control. Among various materials investigated for sensor applications, manganese oxide (MnO2) nanoparticles have garnered significant attention due to their excellent...
In this study, we have investigated the synthesis of supported iridium oxide (IrOx) nanoparticles (NPs) through hydrolysis in a surfactant-free aqueous bath as a possible route for the large-scale production of highly active electrocatalyst for oxygen evolution reaction (OER) in acidic water electrolyzers. The process involves (i) formation of Ir-hydroxides complex from an Ir...
Metal-organic cobalt hydroxide emerges as a cost-effective electrocatalyst for the oxygen evolution reaction (OER) in energy conversion. However, the limited active sites and poor conductivity hinder their large-scale application. This study employed salicylate as a bridging ligand to synthesize iron-incorporated metal-organic cobalt hydroxide. The influence of Fe intercalation...
Ammonia (NH3) is one of the most used chemicals. Industrially, ammonia is produced by hydrogenation of N2 through the Haber–Bosch process, a process in which enormous amounts of CO2 are released and requires a huge energy consumption (~ 2% of the total global energy). Therefore, it is of paramount importance to explore more sustainable and environmentally friendly routes to...
Oxygen defect engineering is a reliable and efficient approach to modulate the electronic structure of metal oxides for the improvement of catalytic efficiency. In this work, carbon nitride supported titanium dioxide nanoparticle, with the space group of I41/amd, was prepared using a high temperature synthesis route. Transmission electron microscope study revealed that titanium...
This study revisits the impacts of the presence of OH− and Cl− anions and/or different forms of Pt precursors during polyol synthesis of carbon-supported electrocatalysts. Efficiency of the synthesis process in terms of the %conversion of a Pt complex to Pt metal has been quantified. It is observed that Pt precursors based on [PtCl6]2− are reduced easily compared to those based...
Polymeric carbon nitrides (C3N4) are photochemically active organic semiconductors that can be produced in a wide range of structural types. Here, a poly-(heptazine imide) containing nickel single atoms (Ni-PHI) is employed for photochemical hydrogen production and is compared to the non-nickel-doped semiconductor. Film deposits are formed on a platinum disk electrode (to detect...
Heavy metals are serious inorganic pollutants that need to be monitored in the hydrosphere with simple and cheap methods. Herein, a new sensor was fabricated by modifying a carbon paste electrode with MgO/Fe2O3 nanocomposite for simple, rapid, accurate, and highly sensitive simultaneous determination of Cd (II) and Cu (II) using differential pulse anodic stripping voltammetry...
This review focuses on monitoring selected organic contaminants utilising an electrochemistry technique due to intrinsic benefits such as simplicity, portability, cost, and improved sensitivity. Because the presence of organic pollutants in water causes a variety of health issues such as tumour, headaches, tiredness, and developmental abnormalities, it is critical to explore an...
Study of the use of polymers with higher conductivity like polypyrrole, and polyaniline in the electrochemical insulin sensors can overcome the drawbacks arising from the ongoing use of non-conductive polymer membrane. Conductive polymer membranes maintain the positive properties of polymers, like improved stability, reproducibility, and even increase the current response of the...
In the bipolar-type alkaline water electrolysis powered by renewable energy, electrocatalysts are degraded by repeated potential change associated with the generation of reverse current. If an electrode has large discharge capacity, the opposite electrode on the same bipolar plate is degraded by the reverse current. In this study, discharge capacity of various transition metal...
The electrocoagulation method using stainless steel anodes was applied to a corrugated cardboard box manufacturing plant’s wastewater with high COD content. The effects of current density, processing time and stirring speed on response functions were studied using the Response Surface Methodology (RSM). The removal efficiency of chemical oxygen demand (COD) and energy consumption...
Lanthanum-based perovskites (LaMnxCo1-xO3 (0 ≤ x ≤ 1)) were synthesized using a solution combustion synthesis technique with variable ratios of Co and Mn to investigate the surface property and electrocatalytic characteristics (stability and activity of catalyst) for methanol oxidation reaction (MOR), oxygen reduction reaction (ORR), and oxygen evolution reaction (OER) under...
The theory of the diffusion limited electrochemical nucleation and growth of a deposit consisting of isolated 3D hemispherical nuclei has been re-analysed. The analysis focuses on a widely discussed model which assumes formation of “diffusion zones” around the growing nuclei. It has been proposed in the literature that the deposit-free fraction of the surface area of the...